Plastics are polymers and can be categorised into thermoplastics and thermosetting plastics based on their properties in terms of strength and heat resistance. That's the classification that underlies their various industrial uses. This comparison shows you the key physical properties of each of these materials and their performance differences.
Thermoplastics are those which can be softened when heated again and then be cut again. It is a feature of their linear or slightly branching polymers, not cross-linked. Thermoplastics tend to be less stiff than thermosetting plastics, and are therefore softer and more malleable for flexible use. But they are a bit coarser than their thermosetting cousins.
Polymer | Density (ρ, kg/m3) | Tensile Strength (σ, MPa) | Elongation (%) | Young's Modulus (E, GPa) | Brinell Hardness Number |
Acrylic (metacrylate) | 1190 | 74 | 6 | 3 | 34 |
Cellulose Acetate | 1300 | 40 | 10 - 60 | 1.4 | 12 |
Cellulose Nitrate | 1350 | 48 | 40 | 1.4 | 10 |
Nylon | 1160 | 60 | 90 | 2.4 | 10 |
Polyethylene | 950 | 20 - 30 | 20 - 100 | 0.7 | 2 |
Polypropylene | 900 | 27 | 200 - 700 | 1.3 | 10 |
Polystyrene | 1050 | 48 | 3 | 3.4 | 25 |
PTFE (fluoropolymer) | 2100 | 13 | 100 | 0.3 | |
PVC | 1330 | 48 | 200 | 3.4 | 20 |
The standard ones are polyethylene (PE), polyvinyl chloride (PVC), and polystyrene (PS), which differ with respect to their mechanical and thermal properties. PE, for example, is prized for being highly chemically resistant and hard, and PVC is used widely in construction due to its resilience and resistance to fire.
When thermosetting plastics are moulded, they're subject to a permanent chemical change called curing. This reaction is induced through heat and pressure to produce a highly cross-linked polymer network. Therefore, the thermosets cannot be resoftened or modified after cure, and hence they are more hard and rigid.
Thermosetting plastics tend to be harder and brittle than thermoplastics and can be used for applications with extreme strength that need to resist heat. Epoxy resins, phenolic resins, and urea-formaldehyde, for instance, are used as coatings, adhesives, or electrical insulators.
Polymer | Density (ρ, kg/m3) | Tensile Strength (σ, MPa) | Elongation (%) | Young's Modulus (E, GPa) | Brinell Hardness Number |
Acetals, glass filled | 1600 | 58 - 75 | 2-7 | 7 | 27 |
Epoxy resin, glass filled | 1600 - 2000 | 68 - 200 | 4 | 20 | 38 |
Melamine formaldehyde, fabric filled | 1800 - 2000 | 60 - 90 | 7 | 38 | |
Phenol formaldehyde, mica filled (phenolic) | 1600 - 1900 | 38 - 50 | 0.5 | 17 - 35 | 36 |
Urea formaldehyde, cellulose filled | 1500 | 38 - 90 | 1 | 7-10 | 51 |
Property | Thermoplastics | Thermosetting Plastics |
Thermal Behavior | Softens upon reheating | Irreversible curing |
Molecular Structure | Linear or slightly branched | Cross-linked network |
Rigidity | Less rigid | More rigid and harder |
Brittleness | Flexible and less brittle | Brittle |
Recyclability | Recyclable through reheating | Non-recyclable after curing |
Common Applications | Packaging, piping, containers | Electrical insulators, coatings |
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