Thermal conductivity is one of the properties of materials that controls their capacity to carry heat. This quality is essential for many industrial and scientific uses, from the optimisation of heat exchangers to building materials. What a variety of materials do when subjected to heat is fundamental to optimizing operations and protecting industrial machinery. Alfa Chemistry provides the table below that summarises the thermal conductivity of the most common materials you will ever come across.
Materials | Thermal Conductivity (W/mK) |
Water | 0.598 |
Air | 0.025 |
Ice | 2.22 |
Glass | 1.05 |
Boron carbide | 30 |
Graphite | 200 |
Carbon fiber | 100 |
Polyethylene | 0.5 |
Polypropylene | 0.2 |
Carbon dioxide | 0.0166 |
Brick | 1.31 |
Porcelain | 1.5 |
Tungsten carbide | 110 |
Diamond | 1000 |
Graphene | 4000 |
PET | 0.3 |
Polycarbonate | 0.2 |
Carbon monoxide | 0.024 |
Sand | 0.25 |
Limestone | 1.3 |
Elektron 21 | 116 |
Duralumin | 140 |
Zirconium-tin alloy | 18 |
Austenitic stainless steel | 20 |
Mild steel | 50 |
Gray iron | 53 |
TZM alloy | 126 |
Inconel | 6.5 |
ETP | 394 |
Cupronickel | 40 |
Zamak 3 | 113 |
Ruby | 40 |
Uranium dioxide | 8.68 |
Polystyrene | 0.12 |
Polyvinyl chloride | 0.2 |
Nitrous oxide | 0.042 |
Concrete | 0.5 |
Granite | 3.2 |
Pure titanium | 22 |
6061 alloy | 150 |
Zirconium-niobium alloy | 18 |
Martensitic stainless steel | 24 |
High-carbon steel | 50 |
White iron | 15-30 |
Mo-25 Re alloy | 70 |
Hastelloy | 10.2 |
Brass | 120 |
Aluminium bronze | 59 |
Soft tin solder | 50 |
Salt | 7 |
Kevlar | 0.04 |
Polyamide-Nylon | 0.2 |
Rubber | 0.5 |
Methan | 0.034 |
Stone wool | 0.3 |
Quartz | 3 |
Ti-6Al-4V | 6.7 |
7068 alloy | 190 |
Chromoly steel | 41 |
Duplex stainless steel | 19 |
Tool steel | 26 |
Ductile iron | 36 |
Tungsten-rhenium alloy | 70 |
Stellite | 14.8 |
Bronze | 75 |
Beryllium copper | 115 |
Amalgam | 23 |
Sugar | 0.15 |
Wax | 0.2 |
Coal | 0.2 |
Asphalt concrete | 0.75 |
Propane | 0.017 |
Glass wool | 0.03 |
Aerogel | 0.01 |
Rose gold | 300 |
Yellow gold | 320 |
White gold | 250 |
PH stainless steel | 18 |
High-speed steel | 41 |
Malleable iron | 40 |
Pure tungsten | 170 |
Invar | 12 |
Constantan | 21.2 |
Nickel silver | 40 |
Galistan | 16.5 |
Oak wood | 0.17 |
Pine wood | 0.12 |
Gasoline | 0.16 |
Diesel fuel | 0.13 |
Acetylene | 0.024 |
What is Thermal Conductivity?
Thermal conductivity (k), measured in watts per meter per Kelvin (W/m·K), quantifies a material's ability to conduct heat. It is very important for the thermal system efficiency. Materials that are very thermally conducting wick heat well, and those that are less thermally conductors are great insulators, blocking the flow of heat. For solids, liquids, and gases, the way in which heat is transferred depends upon what type of substance they are, so their thermodynamics are not the same.
Thermal Conductivity in Solids
Metals: High Conductivity Due to Electron Movement
Metals generally exhibit high thermal conductivity due to the presence of free-moving electrons. These electrons transfer heat more effectively than phonons (the quanta of lattice vibrations). This property makes metals, such as copper, aluminum, and silver, ideal for heat conduction in electrical and mechanical systems. The high electron mobility within metallic structures leads to enhanced heat transfer efficiency, which is crucial in electronics, heat exchangers, and cookware.
Non-Metals: Lattice Vibrations Dominate Heat Transfer
In non-metallic solids, heat conduction is primarily governed by phonons, which are vibrations of the atomic lattice. The efficiency of heat transfer is influenced by the material's atomic structure, with crystalline solids generally exhibiting higher thermal conductivity than amorphous materials. For example, diamond, a crystalline form of carbon, has the highest thermal conductivity among known materials, surpassing even metals like aluminum and copper.
Material | Thermal Conductivity (W/m·K) |
Diamond | 1000 |
Graphite | 119 |
Quartz | 8.7 |
Glass | 1 |
The thermal conductivity of non-metals can be significantly lower than metals, as seen with materials like glass and certain polymers. For instance, graphite has relatively high thermal conductivity, making it suitable for high-temperature applications like heat shields and battery technology.
Thermal Conductivity in Liquids
Unlike solids, where heat conduction is driven by the interaction of atoms in a rigid lattice, liquids conduct heat primarily through molecular diffusion. The distance between molecules in a liquid is greater than in a solid, which reduces the efficiency of heat transfer. However, liquids tend to have higher thermal conductivities than gases due to their denser molecular structure.
Liquid | Thermal Conductivity (W/m·K) |
Water | 0.606 |
Ethanol | 0.171 |
Mercury | 8.3 |
Liquid Sodium | 142 |
Water, for example, is commonly used in cooling systems due to its relatively high thermal conductivity compared to other liquids. Liquid metals, such as mercury, are used in specialized high-temperature applications where efficient heat dissipation is crucial.
Thermal Conductivity in Gases
Gases have much lower thermal conductivities than solids or liquids due to the larger distance between molecules and the lower frequency of collisions. As a result, gases are poor conductors of heat. The thermal conductivity of gases depends on their molecular weight, temperature, and pressure. Lighter gases, such as hydrogen and helium, typically exhibit higher thermal conductivity than heavier gases.
Gas | Thermal Conductivity (W/m·K) |
Hydrogen | 0.442 |
Helium | 0.151 |
Air | 0.026 |
Carbon Dioxide | 0.016 |
Hydrogen, with its small molecular size, has a relatively high thermal conductivity. In contrast, gases like carbon dioxide and air have much lower conductivities, which is why air is often used as an insulator in various industrial applications.
Applications of Thermal Conductivity
Several factors influence the thermal conductivity of materials, including:
- Temperature: Thermal conductivity typically increases with temperature in metals, as electron mobility improves. However, in non-metals, it may decrease due to the increased scattering of phonons at higher temperatures.
- Pressure: In gases, thermal conductivity increases with pressure because the frequency of molecular collisions rises, leading to more efficient heat transfer.
- Material Structure: The atomic or molecular structure plays a significant role in determining thermal conductivity. Crystalline materials tend to have higher conductivities due to their ordered structure, whereas amorphous materials, such as glasses, exhibit lower thermal conductivities.
- Phase of Matter: As a general rule, solids are much better conductors than liquids and gases. However, within each phase, the specific material and its properties determine its efficiency in transferring heat.