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Structure

Sodium Bicarbonate

CAS
144-55-8
Catalog Number
ACM144558-2
Category
Other Products
Molecular Weight
84
Molecular Formula
CHNaO3

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Specification

Description
Sodium bicarbonate (IUPAC name: sodium hydrogen carbonate) is a chemical compound with the formula NaHCO3. It is a salt composed of sodium ions and bicarbonate ions. Sodium bicarbonate is a White solid that is crystalline but often appears as a fine powder. It has a slightly salty, alkaline taste resembling that of washing soda (sodium carbonate). The natural mineral form is nahcolite. It is a component of the mineral natron and is found dissolved in many mineral springs. It is among the food additives encoded by the European Union, identified as E 500. Since it has long been known and is widely used, the salt has many related names such as baking soda, bread soda, cooking soda, and bicarbonate of soda. In colloquial usage, the names sodium bicarbonate and bicarbonate of soda are often truncated. Forms such as sodium bicarb, bicarb soda, bicarbonate, bicarb, or even bica are common. The word saleratus, from Latin sal æratus meaning "aerated salt", was widely used in the 19th century for both sodium bicarbonate and potassium bicarbonate.The prefix "bi" in "bicarbonate" comes from an outdated naming system and is based on the observation that there is twice as much carbonate (CO3) per sodium in sodium bicarbonate (NaHCO3) as there is carbonate per sodium in sodium carbonate (Na2CO3) and other carbonates. The modern way of analyzing the situation based on the exact chemical composition (which was unknown when the name "sodium bicarbonate" was coined) says this the other way around: there is half as much sodium in NaHCO3 as in Na2CO3 (Na versus Na2).
Synonyms
Carbonic acid monosodium salt;Sodium Hydrogen Carbonate;Sodium hydrogencarbonate;Sodium hydrogenocarbonate;sobatum
IUPAC Name
sodium; hydrogen carbonate
Canonical SMILES
C(=O)(O)[O-].[Na+]
InChI
InChI=1S/CH₂O3.Na/c2-1(3)4;/h(H2,2,3,4);/q;+1/p-1
InChI Key
UIIMBOGNXHQVGW-UHFFFAOYSA-M
Boiling Point
851°C
Melting Point
270ºC
Flash Point
169.8ºC
Density
2.159
Solubility
1 in 10 % at 77° F (NTP, 1992);Soluble in water. Insoluble in ethanol;In water, 10.3 g/100 g water at 25 °C;Soluble in 10 parts water at 25 °C; 12 parts water at about 18 °C;Solubility in water = 6.4, 7.6, 8.7, 10.0, 11.3, 12.7, 14.2, 16.5, and 19.1 g/100g solution at 0, 10, 20, 30, 40, 50, 60, 80, and 100 °C, respectively; Solubility in water = 6.9, 8.2, 9.6, 11.1, 12.7, 14.5, 16.5, 19.7, and 23.6 g/100g H₂O at 0, 10, 20, 30, 40, 50, 60, 80, and 100 °C, respectively. Solubility is lower in the presence of sodium carbonate;Insoluble in ethanol;Solubility in water, g/100ml at 20 °C: 8.7
Appearance
White powder or superfime crystal
Color/Form
White, monoclinic prisms;White crystalline powder or granules;White powder or crystalline lumps
Complexity
33.9
Covalently-Bonded Unit Count
2
Decomposition
Hazardous decomposition products formed under fire conditions: Carbon oxides, sodium oxides.;When heated to decomposition it emits acrid smoke, fumes, and carbon dioxide.;Sodium bicarbonate starts decomposing when heated over 50 °C, releasing CO2, H₂O and Na2CO3, with total decomposition at 270 °C.;50 °C
EC Number
205-633-8
Exact Mass
83.9823
Formal Charge
0
H-Bond Acceptor
3
H-Bond Donor
1
Heavy Atom Count
5
HS Code
2836300000
ICSC Number
1044
LogP
-1.11230
MDL Number
MFCD00003528
Monoisotopic Mass
83.9823
Odor
Odorless
Other Experimental
Begins to lose carbon dioxide at about 50 °C and at 100 °C it is converted to sodium carbonate.;Stable in dry air, but slowly decomposes in moist air;MP: 60 °C. Solubility: in water, 7.8 g/100g at 18 °C;Solution of 1.3% is approximately isotonic with body fluids;Readily decomposed by weak acids; in aqueous solution it begins to break up into carbon dioxide and sodium carbonate at about 20 °C and completely on boiling;Alkalinity increase as solutions stand, are agitated, or heated; in liquid mixtures containing bismuth subnitrate, sodium bicarbonate reacts with acid formed by hydrolysis of bismuth salt;1 g neutralizes approximately 120 mL of 0.1 N hydrochloric acid;Specific heat capacity = 87.7 kJ/mol-K at 25 °C;Enthalpy of solution = -18 kJ/mol;Dielectric constant = 4.39 debyes at 25 °C
Physical State
White crystalline powder or granules
PSA
6.36
Refractive Index
1.5
Rotatable Bond Count
0
RTECS Number
VZ0950000
Safety Description
24/25
Stability
Stable.
Storage Conditions
2-8ºC
Supplemental Hazard Statements
H319-H303
Symbol
GHS07
UNII
8MDF5V39QO
Vapor Pressure
2.58E-05mmHg at 25°C
WGK Germany
1

Sodium Bicarbonate/Sodium Carbonate as Accelerator for Portland Cement

Yuli Wang, et al. Materials, 2019, 12(7), 1033.

Sodium bicarbonate (NaHCO3) and sodium carbonate (Na2CO3) can be used as accelerators to improve the rapid hardening ability and high early strength of concrete.
Effect of sodium bicarbonate/sodium carbonate on OPC
· The initial and final setting time of OPC paste decreased with the increase of either NaHCO3 or Na2CO3.
· The addition of either NaHCO3 or Na2CO3 could increase the early age compressive strength depending on the content added.
· As an accelerator, the addition 1% of either of the two accelerators could significantly shorten the setting time, increase the early age strength and did not have an obvious detrimental effect on the later age strength.
· Further increase of NaHCO3 and Na2CO3 above 1% could decrease the compressive strength of OPC paste although the ettringite formation was accelerated and increased.
· NaHCO3 was seen to be a better option as an accelerator compared to Na2CO3. The reaction between NaHCO3 and C3S was found to be much easier than the reaction between Na2CO3 and C3S.

Antimicrobial activity of sodium bicarbonate

Influence of plating medium, inoculum level, and incubation conditions (aerobic versus anaerobic) on the concentration of sodium bicarbonate reouired to inhibit bacterial growth CORRAL, LAURA G., LAURIE S. POST, and THOMAS J. MONTVILLE. Journal of food science 53.3 (1988): 981-982.

Sodium bicarbonate (SB) inhibits the growth of bacteria and yeast in an agar medium model system under certain conditions. Escherichia coli, Lactobacillus plantarum, Staphylococcus aureus, and Pseudomonas aeruginosa counts were reduced by 10,000-fold by 0.12 M (1% wk) SB. Saccharomyces cerevisiae and Hansenula wenkelii were more sensitive at 0.06 M SB; counts were reduced by 100,000-fold. Potassium bicarbonate had the same inhibitory effect, but equimolar sodium chloride had no effect, ruling out osmotic and sodium-mediated mechanisms of inhibition. Bicarbonate ions have been suggested as a possible cause of SB-mediated inhibition, although in some cases, elevated pH played an important role.
Bacterial sensitivity to SB was tested in agar, a general medium for testing antimicrobial compounds, and in media appropriate for specific microorganisms. SB concentrations ranged from 0 to 6%. Media containing potassium bicarbonate (KB) and NaCl in molar amounts equivalent to Na + and HCO 3 were also prepared. Provided by inhibitory SB concentration. The media used as pH controls were adjusted to pH 10 using 5N NaOH. To examine the inhibition of bacteria in liquid systems, citrate phosphate buffers at pH 5.6, 6.0, 7.0 and Tris-HCl buffer at pH 8.6 were used. SB was added to each medium at 0 to 10% and the pH was readjusted with HCl. The control medium without SB was adjusted to pH 9.4 with 5N NaOH. All media were filter sterilized (0.45 pm) and used immediately.

Research on Sodium Bicarbonate for Swimming Performance

Descriptive data of the participants (n = 9) Lindh, A. M., et al. International journal of sports medicine 29.06 (2008): 519-523.

Sodium bicarbonate ingestion has been shown to improve performance in single high-intensity events, possibly due to an increase in buffering capacity, but its effects on single bout swimming performance have not been investigated. The effects of sodium bicarbonate supplementation on 200 m freestyle performance in elite male athletes were investigated. Following a randomized, double-blind counterbalanced design, 9 swimmers completed maximal effort swimming on 3 separate occasions: a control trial (C); following sodium bicarbonate ingestion (SB: NaHCO3 00 mg/kg body weight); and following placebo ingestion (P: CaCO3 200 mg/kg body weight). SB and P agents were packaged in gelatin capsules and taken 90-60 min before each 200 m swim. Mean 200 m performance times were significantly faster with SB than with C or P. Base excess, pH, and blood bicarbonate were elevated before exercise with SB compared to C and P trials (p < 0.05). Blood lactate concentrations after 200 m were significantly higher after the SB test compared to the P and C (p < 0.05). It is concluded that SB supplementation can improve 200 m freestyle performance in elite male athletes, most likely by increasing buffering capacity.
For the SB and P tests, arterial capillary blood samples (90 μl) were collected sequentially at rest (before intake), after intake (55 min after completion of supplementation, i.e., 5 min before performance), and 3 min after performance for measurement of blood pH, base excess (BE), and bicarbonate concentration (HCO) using an iSTAT dry chemistry analyzer. These measurements using the i-STAT analyzer have been found to be reliable previously. In the control test, samples were collected at the post-intake and post-performance time points. To measure the blood lactate response to exercise, additional samples (50 μl) were collected at rest and then 1, 4, and 6 min after exercise and analyzed using a lactate analyzer. Blood lactate analysis using this analyzer has been reported to have high test-retest reliability (r = 0.99, CV < 3%). All blood samples were collected while the subjects were seated.

July 27, 2024


Amazing Results with Sodium Bicarbonate!
I recently used sodium bicarbonate in a dye conjugation reaction and I was amazed by the results! The buffer solution provided an ideal pH of 8.5 for the reaction, resulting in excellent conjugation efficiency. The purity of the conjugated antibody was also top-notch, thanks to the easy purification process involving a G-50 spin column. Overall, sodium bicarbonate greatly enhanced the success of my experiment and I highly recommend it to anyone working with dye conjugation reactions.

What is the molecular formula of sodium bicarbonate?

The molecular formula of sodium bicarbonate is NaHCO3.

What is the molecular weight of sodium bicarbonate?

The molecular weight of sodium bicarbonate is 84.007 g/mol.

What is the IUPAC name of sodium bicarbonate?

The IUPAC name of sodium bicarbonate is sodium;hydrogen carbonate.

What is the InChI key of sodium bicarbonate?

The InChI key of sodium bicarbonate is UIIMBOGNXHQVGW-UHFFFAOYSA-M.

What is the canonical SMILES of sodium bicarbonate?

The canonical SMILES of sodium bicarbonate is C(=O)(O)[O-].[Na+].

What is the CAS number of sodium bicarbonate?

The CAS number of sodium bicarbonate is 144-55-8.

What is the EC number of sodium bicarbonate?

The EC number of sodium bicarbonate is 205-633-8.

What is the UNII of sodium bicarbonate?

The UNII of sodium bicarbonate is 8MDF5V39QO.

What is the ChEMBL ID of sodium bicarbonate?

The ChEMBL ID of sodium bicarbonate is CHEMBL1353.

What is the Wikipedia page for sodium bicarbonate?

The Wikipedia page for sodium bicarbonate is Sodium bicarbonate.

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