1291-48-1 Purity
97%
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Specification
Glycerol ethoxylate as an ignition improver has an effect on the injection and combustion characteristics of hydrous ethanol under CI engine conditions. The injection characteristics were investigated by an in-house injection rate measurement device based on the Zeuch method, while spray combustion was performed in a rapid compression expander (RCEM). The CI engine conditions represent the density, pressure and temperature of compressed synthetic gas (composed of 80% argon and 20% oxygen) and the fuel injection timing in the RCEM at 21 kg/m, 4.4 MPa and 900 K, respectively. This condition is equivalent to the isentropic compression of air in a real CI engine with a compression ratio of 22. Hydrous ethanol without ignition improver and heavy-duty vehicle ethanol are reference fuels representing low-quality and high-quality ethanol fuels for CI engines, respectively. All test fuels were injected at a constant heat input. The results show that the additional ignition improver changes the injection characteristics of hydrous ethanol, namely injection delay, injection rate and emission coefficient. The maximum injection rate of heavy-duty vehicle ethanol and hydrous ethanol with 5% glycerol ethoxylate (5%GE) at fully opened needle was about 10% lower than that of hydrous ethanol without ignition improver (Eh95). ED95 and 5%GE required additional injection duration to maintain constant energy input. Ignition improvers significantly improved the ignition delay and heat release rate of Eh95. The effect of ignition improvers on flame temperature was minimal. The KL factor was approximately proportional to the amount of soot in the light path, and the measured soot emission was affected by these improvers.
The effect of ignition improvers on combustion characteristics was focused on, and the important parameters affecting ignition and combustion, namely, in-cylinder gas temperature and pressure at injection, nozzle orifice, oxygen concentration, and injection pressure were fixed. Glycerol ethoxylate and commercial additive ED95 were used as ignition improvers. The three fuels considered in this study are hydrous ethanol without ignition improvers (Eh95); commercial ethanol fuel (ED95) consisting of hydrous ethanol and commercial additives for ED95; and hydrous ethanol containing 5 wt% glycerol ethoxylate (5% GE). The composition of ED95 in Table 1 is expressed as mass fraction. With this mass composition, ED95 becomes 95% hydrous ethanol and 5% commercial additives by volume. For Eh95, 1% by weight of lauric acid is added to hydrous ethanol to prevent injection system lubrication failure. However, lauric acid is not added to ED95 because it already contains lubricants in commercial additives. Eh95 and ED95 are used to represent ethanol fuels with low ignition quality fuels and high ignition quality fuels for CI engines.
In order to modify the properties of starch films, various plasticizers are added. Water and glycerol are usually used as plasticizers. Starch films were obtained from potato starch by the casting technique using glycerol derivatives as modern plasticizers, resulting in films of constant thickness and length of 20 cm. The influence of the ratio of various plasticizers: glycerol, pentaerythritol ethoxylate, glycerol ethoxylate and Poligliceryn-3 on the mechanical properties and surface free energy was studied. The selected plasticizers are characterized by a high number of functional groups hydroxyl groups. Starch films containing the plasticizer mixture show better usable properties and higher mechanical properties than starch films using only one plasticizer. However, glycerol derivatives cannot be used without the addition of glycerol. In addition, the surface free energy was determined by the OwensWendt and van Oss-Chaudhury-Good methods. The values of SFE were in the range of 50-60 mJ/man, which are higher than those of typical plastic films used in the packaging industry. The resulting starch film is characterized by a high SFE polar component, which may be related to the influence of hydroxyl groups.
A certain amount of glycerol or glycerol derivatives such as Glycerol ethoxylate was added to a solution of 4 g starch in 100 g water. Next, the film-forming suspension was heated and continuously mixed to above 95 °C for 5 minutes and then cooled to 50 °C to obtain a film-forming solution. The film-forming solution was cast on a polytetrafluoroethylene-coated plate, which was placed on an applicator equipped with an applicator with a gap of 3 mm. The film was dried at room temperature and humidity 30% RH. The contact angle of the resulting film was measured using a DSA 30E drop shape analysis system. To measure the contact angle, a smooth and horizontal sessile drop of the liquid was deposited on a solid surface using a needle with a diameter of 0.5 mm. The contact angle was measured on a static drop. The drop shape analysis was performed using the tangent method 2 after 15 seconds of drop deposition. The environmental conditions were stable and the temperature was 23 ± 0.5 °C. The reported contact angle values are the average of 6 probes on two films. SFE was calculated using the Owens-Wendt and van-OssyGood methods.
The IUPAC name of Glycerol ethoxylate is 2-[2,3-bis(2-hydroxyethoxy)propoxy]ethanol.
The molecular weight of Glycerol ethoxylate is average Mn ~1000.
Glycerol ethoxylate is commonly expressed as R1-(O-CH2-CH2)n-O-R2, where n represents the number of ethylene glycol units.
The boiling point of Glycerol ethoxylate is greater than 200 °C.
PEG compounds are generally described as biocompatible, non-toxic, and stable in both organic and aqueous solutions.
Activated PEG derivatives can be used to modify peptides, proteins, or in other bioconjugation applications.
PEGylation can improve properties such as increased water solubility, enhanced resistance to degradation, increased circulation half-life, and reduced antigenicity.
Some features and benefits of Glycerol ethoxylate include high quality products, fast delivery, and the option to order additional products.
Functionalized PEG lipids and phospholipids can be used for protein-PEG conjugation, drug delivery systems, virology, immunology, and in tissue engineering applications.
The EC number of Glycerol ethoxylate is 500-075-4; 244-250-0.