Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]

CAS

374067-50-2

Catalog Number

ACM374067502

Category

Ruthenium series catalysts

Molecular Weight

956.078g/mol

Molecular Formula

C56H56O4P2Ru;

MSDS COA Spec Sheet

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Specification

Synonyms

DIACETATO[(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL]RUTHENIUM(II); RU(OAC)2[(S)-XYLBINAP]; 374067-50-2; Diacetoxyruthenium; RU(OAC)2[(R)-XYLBINAP]; (R)-Ru(OAc)2(DM-BINAP); DIACETATO[(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL]RUTHENIUM(II); Ru[(S)-DM-BINAP](OCOCH3)2; 374067-49-9; MFCD09753022;

IUPAC Name

acetic acid;[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;ruthenium;

Canonical SMILES

CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC(=O)O.CC(=O)O.[Ru];

InChI

InChI=1S/C52H48P2.2C2H4O2.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;2*1-2(3)4;/h9-32H,1-8H3;2*1H3,(H,3,4);;

InChI Key

HDUAMHMUQGCXCT-UHFFFAOYSA-N;

Application

Catalyst system used for asymmetric hydrogenation.

Storage

2-8°C

Complexity

1080

Covalently-Bonded Unit Count

Exact Mass

956.27g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

956.27g/mol

Rotatable Bond Count

Topological Polar Surface Area

74.6A^2

April 6, 2023

Excellent catalysts in enantioselective hydrogenation
A very good catalyst for the enantioselective hydrogenation of Z-olefins (9-(Z)) to synthesize the acidic segment of the acyl-CoA:cholesterol acyltransferase (ACAT) inhibitor R-106578.

What is the Molecular formula of Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]?

C56H56O4P2Ru

What is the Molecular weight of Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]?

956.1

What is the Melting point of Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]?

>100°C

What is the Storage condition of Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]?

2-8°C

What is the EC number of Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]?

844-065-0

What is the Form of Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]?

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