Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]

• CAS: 374067-51-3
• Catalog Number: ACM374067513
• Category: Ruthenium series catalysts
• Molecular Weight: 851.926g/mol
• Molecular Formula: C48H48O4P2Ru
• Synonyms: DIACETATO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL]RUTHENIUM(II); RU(OAC)2[(S)-H8-BINAP]; DIACETATO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL]RUTHENIUM(II); RU(OAC)2[(R)-H8-BINAP]; 142962-95-6; Diacetato[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-5,5 inverted exclamation marka,6,6 inverted exclamation marka,7,7 inverted exclamation marka,8,8 inverted exclamation marka-octahydro-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); Diacetato[(R)-2,2 inverted exclamation marka-bis(diphenylphosphino)-5,5 inverted exclamation marka,6,6 inverted exclamation marka,7,7 inverted exclamation marka,8,8 inverted exclamation marka-octahydro-1,1 inverted exclamation marka-binaphthyl]ruthenium(II)
• IUPAC Name: acetic acid;[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;ruthenium
• Canonical SMILES: CC(=O)O.CC(=O)O.C1CCC2=C(C1)C=CC(=C2C3=C(C=CC4=C3CCCC4)P(C5=CC=CC=C5)C6=CC=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]
• InChI: InChI=1S/C44H40P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-12,19-26,29-32H,13-18,27-28H2;2*1H3,(H,3,4)
• InChI Key: BWYPLACAJUYPKL-UHFFFAOYSA-N
• Application: Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.; ; The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
• Storage: 2-8°C
• Complexity: 875
• Covalently-Bonded Unit Count: 4
• Exact Mass: 852.207g/mol
• H-Bond Acceptor: 4
• H-Bond Donor: 2
• Heavy Atom Count: 55
• Monoisotopic Mass: 852.207g/mol
• Rotatable Bond Count: 7
• Topological Polar Surface Area: 74.6A^2

Custom Reviews

April 6, 2023

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Good catalyst in the hydrogenation of carboxylic acid 4c
The catalyst effectively catalyzed the hydrogenation reaction of carboxylic acid 4c, yielding a quantitative yield of (R)-1 and 85% ee.

Custom Q&A

What is the Molecular formula of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

C48H48O4P2Ru

What is the Molecular weight of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

851.9

What is the Melting point of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

>100°C

What is the Storage condition of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

2-8°C

What is the EC number of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

622-528-6

What is the Form of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

Powder

What is the Sensitivity of Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap]?

Air sensitive