Bis(dibutyldithiocarbamato-s,s')copper

• CAS: 13927-71-4
• Catalog Number: ACM13927714
• Category: Main Products
• Molecular Weight: 472.30
• Molecular Formula: C₁₈H₃₆CuN₂S₄
• Synonyms: Copper dibutyldithiocarbamate, Bis(dibutyldithiocarbamato)copper, Copper(II) dibutyldithiocarbamate, Copper bis(dibutyldithiocarbamate), Copper(2+) dibutyldithiocarbamate, EINECS 237-695-7, NSC 22318, AIDS011576, Bis(dibutyldithiocarbamato-S,S)copper, AIDS-011576, NSC22318, EINECS 258-105-4, Bis(dibutylcarbamodithioato-S,S)copper, LS-49236, Copper, bis(dibutyldithiocarbamato)- (VAN), Copper, bis(dibutyldithiocarbamato)- (7CI,8CI), CARBAMIC ACID, DIBUTYLDITHIO-, COPPER(II) SALT, Copper bis(dibutylcarbamodithioato-S,S)-, (SP-4-1)-, Copper, bis(dibutyldithiocarbamato)- (VAN) (8CI), Copper, bis(dibutylcarbamodithioato-S,S)-, (SP-4-1)-
• IUPAC Name: copper N,N-dibutylcarbamodithioate
• InChI Key: IXPUJMULXNNEHS-UHFFFAOYSA-L
• Boiling Point: 257.7ºC at 760 mmHg
• Melting Point: 73 0ºC
• Flash Point: 109.6ºC
• Appearance: Dark Blackish Blue Powder
• Exact Mass: 471.10600
• H-Bond Acceptor: 2
• H-Bond Donor: 0

Case Study

Copper Dibutyldithiocarbamate for the Preparation of Copper Sulfide Nanocrystals for Photocatalysis

Estrada, Ana C., et al. RSC advances, 2016, 6(41), 34521-34528.

Copper sulfide nanomaterials were prepared by a single-source approach through the pyrolysis of Cu(II) dialkyldithiocarbamate complexes, including copper diethyldithiocarbamate {Cu[S2CN(C2H5)2]2}, and copper dibutyldithiocarbamate {Cu[S2CN(C4H9)2]2}, in ionic liquids. The photocatalytic activity of the prepared copper sulfide nanocrystals in the degradation of rhodamine B (RhB) was preliminarily evaluated. The results showed that the best degradation values of RhB were obtained in the presence of djurleite and digenite prepared in ionic liquids, with the degradation rate reaching almost 100% after 120 min.
Synthesis procedure of copper sulfide nanocrystals
· Copper sulphide nanocrystals were synthesized via thermolysis in the ionic liquids [THTDP][N(CN)2] and [THTDP][NTf2] using two approaches: hot-injection and batch.
· Hot-injection: 0.233 mmol of precursor (copper diethyldithiocarbamate or copper dibutyldithiocarbamate) was dissolved in 4 mL of IL and rapidly injected into 16 mL of hot IL under N2. The reaction mixture was maintained at the desired temperature for 3 hours, then cooled to 45 °C, and precipitated with methanol. The solid product was isolated by centrifugation and washed with methanol.
· Batch: 0.233 mmol of precursor was dissolved in 20 mL of IL under N2 and heated at the desired temperature for 3 hours. The nanocrystals were isolated as described for the hot-injection method.

Custom Reviews

August 13, 2023

---

Useful polymerization inhibitor
Bis(dibutyldithiocarbamato-s,s')copper can effectively block the polymerization reaction of polymer, and it is a very useful polymerization inhibitor.

Custom Q&A

What is the molecular formula of Bis(dibutyldithiocarbamato-s,s')copper?

The molecular formula of Bis(dibutyldithiocarbamato-s,s')copper is C18H36CuN2S4.

What are the synonyms of Bis(dibutyldithiocarbamato-s,s')copper?

Some synonyms of Bis(dibutyldithiocarbamato-s,s')copper are Copper dibutyldithiocarbamate, Copper(II) dibutyldithiocarbamate, Bis(dibutyldithiocarbamato)copper, Copper bis(dibutyldithiocarbamate), and Copper(2+) dibutyldithiocarbamate.

What is the CAS number of Bis(dibutyldithiocarbamato-s,s')copper?

The CAS number of Bis(dibutyldithiocarbamato-s,s')copper is 52691-95-9.

What is the IUPAC name of Bis(dibutyldithiocarbamato-s,s')copper?

The IUPAC name of Bis(dibutyldithiocarbamato-s,s')copper is copper;N,N-dibutylcarbamodithioate.

What is the InChIKey of Bis(dibutyldithiocarbamato-s,s')copper?

The InChIKey of Bis(dibutyldithiocarbamato-s,s')copper is IXPUJMULXNNEHS-UHFFFAOYSA-L.

What is the molecular weight of Bis(dibutyldithiocarbamato-s,s')copper?

The molecular weight of Bis(dibutyldithiocarbamato-s,s')copper is 472.3g/mol.

How many hydrogen bond acceptor counts does Bis(dibutyldithiocarbamato-s,s')copper have?

Bis(dibutyldithiocarbamato-s,s')copper has 4 hydrogen bond acceptor counts.

What is the topological polar surface area of Bis(dibutyldithiocarbamato-s,s')copper?

The topological polar surface area of Bis(dibutyldithiocarbamato-s,s')copper is 72.7Ų.

How many rotatable bond counts does Bis(dibutyldithiocarbamato-s,s')copper have?

Bis(dibutyldithiocarbamato-s,s')copper has 12 rotatable bond counts.

What is the complexity of Bis(dibutyldithiocarbamato-s,s')copper?

The complexity of Bis(dibutyldithiocarbamato-s,s')copper is 112.