Triisopropylsilyltrifluoromethanesulfonate

• CAS: 80522-42-5
• Catalog Number: ACM80522425
• Category: Siloxanes
• Molecular Weight: 306.41 g/mol
• Molecular Formula: C10H21F3O3SSi
• Synonyms: Tipsotftriisopropyl(Trifluoromethanesulfonato)Silanetriisopropylsilyltriflatetipstriflate1,1,1-Trifluoromethanesulfonicacidtris(1-Methylethyl)Silylestertriisopropylsilyltrifluoromethanesulfonatetris(1-Methylethyl)Silyltrifluoromethanesulfonatetrifluoromethanesulfonicacidtriisopropylsilylestertipstriflatesilaneip3-Triflateseemoresynymstips-Otf(I-Pr)3Siotf
• IUPAC Name: tri(propan-2-yl)silyltrifluoromethanesulfonate
• Canonical SMILES: CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F
• InChI Key: LHJCZOXMCGQVDQ-UHFFFAOYSA-N
• Boiling Point: 45-46 °C0.03 mmHg)
• Flash Point: 213 °C
• Density: 1.14 g/mL(25 °C,lit.)
• Appearance: Clear Colourless Oil
• Exact Mass: 306.09300
• Hazard Statements: C:Corrosive
• Packaging: 10 g; 100 g
• Packing Group: II
• Safety Description: S26-S27-S28-S36/37/39-S45
• WGK Germany: 3

Custom Q&A

What is the molecular formula of Triisopropylsilyltrifluoromethanesulfonate?

The molecular formula is C10H21F3O3SSi.

What is the molecular weight of Triisopropylsilyltrifluoromethanesulfonate?

The molecular weight is 306.42 g/mol.

What is the IUPAC name of Triisopropylsilyltrifluoromethanesulfonate?

The IUPAC name is tri(propan-2-yl)silyl trifluoromethanesulfonate.

What is the InChI of Triisopropylsilyltrifluoromethanesulfonate?

The InChI is InChI=1S/C10H21F3O3SSi/c1-7(2)18(8(3)4,9(5)6)16-17(14,15)10(11,12)13/h7-9H,1-6H3.

What is the InChIKey of Triisopropylsilyltrifluoromethanesulfonate?

The InChIKey is LHJCZOXMCGQVDQ-UHFFFAOYSA-N.

What is the canonical SMILES of Triisopropylsilyltrifluoromethanesulfonate?

The canonical SMILES is CC(C)[Si](C(C)C)(C(C)C)OS(=O)(=O)C(F)(F)F.

What is the CAS number of Triisopropylsilyltrifluoromethanesulfonate?

The CAS number is 80522-42-5.

What is the EC number of Triisopropylsilyltrifluoromethanesulfonate?

The EC number is 638-988-6.

Is Triisopropylsilyltrifluoromethanesulfonate a canonical compound?

Yes, Triisopropylsilyltrifluoromethanesulfonate is a canonical compound.

Synthetic Use

Upstream Synthesis Route 1

• 6485-79-6
• 1493-13-6

• 80522-42-5

Reference: [1] Tetrahedron Letters, 1981, vol. 22, # 36, p. 3455 - 3458
[2] Advanced Synthesis and Catalysis, 2009, vol. 351, # 7-8, p. 1035 - 1040
[3] European Journal of Organic Chemistry, 2017, vol. 2017, # 17, p. 2512 - 2539
[4] European Journal of Organic Chemistry, 2017, vol. 2017, # 20, p. 2883 - 2915

Upstream Synthesis Route 2

• 1493-13-6
• 24400-84-8

• 80522-42-5

Reference: [1] Synthesis, 1997, # 7, p. 744 - 746

Upstream Synthesis Route 3

• 13154-24-0
• 1493-13-6

• 80522-42-5

Reference: [1] Bulletin of the Chemical Society of Japan, 1990, vol. 63, # 4, p. 1039 - 1048
[2] Tetrahedron Letters, 1987, vol. 28, # 49, p. 6191 - 6194

Downstream Synthesis Route 1

• 6881-49-8
• 80522-42-5

• 137812-10-3

Reference: [1]Canadian Journal of Chemistry,1991,vol. 69,p. 1487 - 1497

Downstream Synthesis Route 2

• 6710-62-9
• 16075-82-4
• 80522-42-5

• 133721-57-0

Reference: [1]Obrecht, Daniel
[Helvetica Chimica Acta, 1991, vol. 74, # 1, p. 27 - 46]
[2]Obrecht, Daniel
[Helvetica Chimica Acta, 1991, vol. 74, # 1, p. 27 - 46]

Downstream Synthesis Route 3

• 69778-83-2
• 80522-42-5

• 109826-87-1

Reference: [1]Tetrahedron Letters,1986,vol. 27,p. 5285 - 5288

* For details of the synthesis route, please refer to the original source to ensure accuracy.