Structure

Bis(Trimethylsilyl)Malonate

CAS
18457-04-0
Catalog Number
ACM18457040
Category
Siloxanes
Molecular Weight
0.972 g/mol
Molecular Formula
C9H20O4Si2

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Specification

Synonyms
Malonicacidbis(Trimethylsilyl)EsterCTadecylsilane
IUPAC Name
bis(trimethylsilyl)propanedioate
Canonical SMILES
C[Si](C)(C)OC(=O)CC(=O)O[Si](C)(C)C
InChI Key
ATCKJLDGNXGLAO-UHFFFAOYSA-N
Boiling Point
63ºC(1 torr)
Flash Point
65.3ºC
Density
1 g/mL
Appearance
Transparent liquid
Application
Bis(trimethylsilyl)malonate serves as a versatile chemical reagent with a primary purpose of facilitating cyclocondensation reactions particularly in the synthesis of β-keto acids and methyl ketones Additionally it acts as a precursor in the metal-organic chemical vapor deposition (MOCVD) process for creating thin films of HfO2 and ZrO2 The compound is also involved in acylation reactions with acid chlorides and acyl carbonates where in the presence of triethylamine and magnesium or lithium salts it efficiently yields β-keto acids or methyl ketones
EC Number
242-342-5
Exact Mass
248.09000
Hazard Statements
F: Flammable;
Packing Group
III
Safety Description
16
WGK Germany
3
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