Chloro(1,5-cyclooctadiene)rhodium(I) dimer

CAS

12092-47-6

Catalog Number

ACM12092476-2

Category

Rhodium series of catalysts

Molecular Weight

493.08

Molecular Formula

C16H24Cl2Rh2

MSDS COA Spec Sheet

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Specification

Synonyms

Bis(cycloocta-1,5-diene)dichlorodirhodium

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride;

Canonical SMILES

C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh]

InChI

InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H,3-6H2;2*1H;/p-2/b2*2-1-,8-7-;

InChI Key

PDJQCHVMABBNQW-MIXQCLKLSA-L

Melting Point

243 °C

Appearance

Orange yellow powder

Application

Catalyst for coupling 1,3-dienes with activate methylene compounds.

Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.

Rhodium source for asymmetric reductive aldol reaction.

Cis-hydroboration of terminal alkynes.

Rhodium source for [5 + 2] additions.

Highly enantioselective for [2+2+2] carbocyclization reactions.

Enantioselective hydroboration of cyclopropenes.

Storage

2-8°C

Complexity

72.6

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Defined Bond Stereocenter Count

EC Number

235-157-6

Exact Mass

491.93649

Formal Charge

-2

H-Bond Acceptor

Heavy Atom Count

Hydrogen Bond Acceptor Count

Hydrogen Bond Donor Count

Isomeric SMILES

C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.[Cl-].[Cl-].[Rh].[Rh]

Monoisotopic Mass

491.93649

Rotatable Bond Count

Topological Polar Surface Area

0 Å²

What is the molecular formula of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The molecular formula is C16H24Cl2Rh2.

What is the molecular weight of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The molecular weight is 493.1 g/mol.

What is the IUPAC name of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The IUPAC name is (1Z,5Z)-cycloocta-1,5-diene;rhodium;dichloride.

What is the InChI of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The InChI is InChI=1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/p-2/b2*2-1-,8-7-;;;;.

What is the InChIKey of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The InChIKey is PDJQCHVMABBNQW-MIXQCLKLSA-L.

What is the canonical SMILES of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The canonical SMILES is C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh].

What is the CAS number of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The CAS number is 12092-47-6.

What is the European Community (EC) number of Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

The European Community (EC) number is 235-157-6.

How many covalently-bonded units are present in Chloro(1,5-cyclooctadiene)rhodium(I) Dimer?

There are 6 covalently-bonded units in Chloro(1,5-cyclooctadiene)rhodium(I) Dimer.

What are some synonyms of Chloro(1,5-cyclooctadiene)rhodium(I) dimer?

Some synonyms include Bis(1,5-cyclooctadiene)dirhodium(I) dichloride and Chloro(1,5-cyclooctadiene) rhodium (I) dimer.

When was Chloro(1,5-cyclooctadiene)rhodium(I) dimer created?

It was created on April 28, 2006.

How many hydrogen bond donor counts does Chloro(1,5-cyclooctadiene)rhodium(I) dimer have?

It has 0 hydrogen bond donor counts.

How many rotatable bond counts does Chloro(1,5-cyclooctadiene)rhodium(I) dimer have?

It has 0 rotatable bond counts.