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Structure

Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate

CAS
36620-11-8
Catalog Number
ACM36620118
Category
Rhodium series of catalysts
Molecular Weight
373.991g/mol
Molecular Formula
C14H16BF4Rh-;

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Specification

Synonyms
36620-11-8; Bis(norbornadiene)rhodium(I) tetrafluoroborate; [rh(nbd)2]bf4; SC-49716; Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate; ANW-41403; MFCD00671775; Bis(norbornadiene)(tetrafluoroborato)rhodium; bis(norbomadiene)rhodium (I) tetrafluoroborate; Bis(norbornadiene)rhodium (I) tetrafluoroborate;
IUPAC Name
bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborate;
Canonical SMILES
[B-](F)(F)(F)F.C1C2C=CC1C=C2.C1C2C=CC1C=C2.[Rh];
InChI
InChI=1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;;
InChI Key
ZWPWNBFOFVFMPP-UHFFFAOYSA-N;
Application
Bis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.
Storage
Refrigerator
Complexity
122
Covalently-Bonded Unit Count
4
Exact Mass
374.034g/mol
Formal Charge
-1
H-Bond Acceptor
5
Heavy Atom Count
20
Monoisotopic Mass
374.034g/mol
Topological Polar Surface Area
0A^2
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