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Structure

Ammonium tetrafluoroborate

CAS
13826-83-0
Catalog Number
ACM13826830-6
Category
Main Products
Molecular Weight
104.85
Molecular Formula
BF4H4N

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Specification

Description
Ammonium fluoborate appears as odorless white crystals. Sinks and mixes with water. (USCG, 1999)
Synonyms
Ammonium fluoborate
IUPAC Name
Azanium;tetrafluoroborate
Canonical SMILES
[B-](F)(F)(F)F.[NH4+]
InChI
InChI=1S/BF4.H3N/c2-1(3,4)5;/h;1H3/q-1;/p+1
InChI Key
PDTKOBRZPAIMRD-UHFFFAOYSA-O
Melting Point
230 °C
Density
1.871 g/mL at 25 °C(lit.)
Solubility
Soluble in water
Appearance
White powder
Storage
Inert atmosphere,Room Temperature
Autoignition Temperature
Not flammable (USCG, 1999)
Color/Form
White powder, orthorhombic
Complexity
19.1
Corrosivity
Corrosive to aluminum
Covalently-Bonded Unit Count
2
Decomposition
When heated to decomposition it emits very toxic fumes of /hydrogen fluoride and nitrogen oxides and ammonia./;The toxic action of the halogenated borons is considerably influenced by their decomposition products (hydrofluoric acid-, fluoboric acid-, hydrochloric acid-). /Halogenated borons/
EC Number
237-531-4
Exact Mass
105.0372919
Formal Charge
0
H-Bond Acceptor
5
H-Bond Donor
1
Heavy Atom Count
6
Monoisotopic Mass
105.0372919
Odor
Odorless
Other Experimental
Heat of sublimation: 144 BTU/lb= 80.2 cal/g= 3.36X10+5 J/kg;Sublimes at melting point
Rotatable Bond Count
0
Topological Polar Surface Area
1 Ų
UNII
C945Z80O8X
UN Number
1759;3077
Vapor Pressure
0.001 lb/sq inch at 100 °F

Cellulose Acetate-Ammonium Tetrafluoroborate-Based Polymer Electrolyte

Harun N I, et al. Materials Research Innovations, 2011, 15(sup2), s168-s172.

Proton conducting polymers were prepared using cellulose acetate (CA) as the main polymer and ammonium tetrafluoroborate (NH4BF4) as the proton source complex. In order to improve the performance of the proton conducting polymer, polyethylene glycol 600 (PEG) was introduced as a plasticizer. The conductivity study results showed that the temperature dependence of both CA-NH4BF4 and CA-NH4BF4-PEG600 systems exhibited Arrhenius behavior.
Preparation of plasticised polymer electrolyte
· Preparation of CA-NH4BF4
A total of one gram of CA was dissolved in 30 mL of acetone, stirring with a magnetic stirrer for 12 hours. Subsequently, varying weight percentages (ranging from 5 to 45 wt-%) of NH4BF4 were introduced into the polymer solution, which was continuously stirred for a minimum of 24 hours at room temperature (27°C) to ensure a homogeneous mixture. Each resultant sample was then poured into Petri dishes and allowed to dry for several days, forming a thin film.
· Preparation of CA-NH4BF4-PEG600
The plasticized polymer electrolytes were created by incorporating PEG600 as a plasticizer into the optimal CA-NH4BF4 solution, using various weight percentages from 0 to 40 wt-% to achieve the highest conductivity in the salted sample. All samples were produced utilizing the solution cast technique.

Synthesis of ZIF67 Derivatives Induced by Ammonium Tetrafluoroborate

Kuo T R, et al. Journal of Energy Storage, 2023, 68, 107831.

Ammonium tetrafluoroborate (NH4BF4) was used as a structure directing agent (SDA) for the synthesis of zeolitic imidazolate framework 67 (ZIF67) derivatives, which were then annealed at various temperatures for oxidation to form cobalt nickel oxides as electroactive materials. The study showed that the novel SDA of NH4BF4 is promising for the design of other effective electroactive materials for efficient energy storage.
The resulting oxidized ZIF67 derivatives exhibited a unique leaf-like structure and a composition of cobalt/nickel oxides, irrespective of the oxidation temperature. The oxidized ZIF67 derivative created at 450 °C achieved the highest capacitance factor (CF) of 828.9 F/g, attributed to its advantageous two-dimensional (2D) leaf-like structure and (311) crystal facet. In comparison, the oxidized ZIF67 and the original ZIF67 electrodes recorded CF values of 519.9 and 5.0 F/g, respectively.
The optimized battery system utilizing the oxidized ZIF67 derivative as the positive electrode and graphene as the negative electrode demonstrated an impressive energy density of 10.2 Wh/kg at a power density of 357 W/kg, along with a CF retention of 91% and a Coulombic efficiency of 97% following 10,000 charge/discharge cycles. The novel SDA of NH4BF4 is expected to be used to design other effective electroactive materials for efficient energy storage.

What is the molecular formula of ammonium fluoborate?

The molecular formula of ammonium fluoborate is BF4.H4N or BF4H4N.

What is the molecular weight of ammonium fluoborate?

The molecular weight of ammonium fluoborate is 104.85 g/mol.

What are the synonyms for ammonium fluoborate?

The synonyms for ammonium fluoborate are ammonium tetrafluoroborate, ammonium fluoroborate, and AMMONIUM FLUOBORATE.

When was ammonium fluoborate created?

Ammonium fluoborate was created on October 25, 2006.

When was ammonium fluoborate last modified?

Ammonium fluoborate was last modified on December 2, 2023.

What does ammonium fluoborate look like?

Ammonium fluoborate appears as odorless white crystals.

How does ammonium fluoborate react with water?

Ammonium fluoborate sinks and mixes with water.

What is the IUPAC name of ammonium fluoborate?

The IUPAC name of ammonium fluoborate is azanium;tetrafluoroborate.

What is the InChIKey of ammonium fluoborate?

The InChIKey of ammonium fluoborate is PDTKOBRZPAIMRD-UHFFFAOYSA-O.

What is the CAS number of ammonium fluoborate?

The CAS number of ammonium fluoborate is 13826-83-0.

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