Structure

1,1'-Bis(diisopropylphosphino)ferrocene

CAS
97239-80-0
Catalog Number
ACM97239800
Category
Organic Phosphine Compounds
Molecular Weight
418.32
Molecular Formula
C22H36FeP2

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Specification

Synonyms
1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;
IUPAC Name
1,1-Bis(diisopropylphosphino)ferrocene
Melting Point
50-52ºC(lit.)
Flash Point
>230 °F
Appearance
Orange-yellow powder
Application
Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes

Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.

Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides

Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters

Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation

Ligand for ruthenium-catalyzed C-C coupling reactions of fluorinated alcohols with allenes.

Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
Exact Mass
418.16400
Hazard Statements
Xi: Irritant;
Safety Description
37/39-26
WGK Germany
3
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