Phthalocyanine Tin(II)

• CAS: 15304-57-1
• Catalog Number: ACM15304571
• Category: Main Products
• Molecular Weight: 631.24
• Molecular Formula: C32H16N8Sn
• Appearance: Purple powder

Case Study

Transition Metal Coordination Complexes of Phthalocyanine Tin(II)

Konarev, Dmitri V., et al. Inorganic Chemistry, 2016, 55(4), 1390-1402.

This work describes a method for preparing transition metal complexes of tin(II) phthalocyanine (Sn^IIPc) in the neutral, monoanionic, and dianionic states, taking advantage of the ability of tin atoms to form stable Sn-M bonds with transition metals (Mo, Fe, Rh, and Ru). This method can be used to develop magnetic and conductive components based on metal phthalocyanines and transition metals.
· Key Conclusions
Except for CpFe(CO)2, the negative charge and spin of the coordinated [Sn^IIPc(3-)]·- radical anions were maintained, allowing these anions to function as anionic paramagnetic ligands for the transition metals. In the coordination complex formed between CpFe^I(CO)2 and [Sn^IIPc(3-)]·- (4), an unusual charge transfer occurred, resulting in the generation of {CpFe^II(CO)2}+ cations and [Sn^IIPc(4-)]2- dianions. Additionally, it was discovered that the formally neutral Ph5CpRu^II(CO)2[Sn^IIPc] molecule contains [Sn^IIPc(3-)]·- radical anions, making it particularly noteworthy due to its exhibiting strong magnetic spin coupling.
· Synthesis Case
The compound {Cryptand(Na+)}[Sn^IIPc(3-)]·-·C6H4Cl2 (3) was synthesized by reducing Sn^IIPc (26.4 mg, 0.042 mmol) with a slight excess of sodium fluorenone ketyl (11 mg, 0.054 mmol) in the presence of 1 equivalent of cryptand (16 mg, 0.042 mmol) in o-dichlorobenzene (16 mL) at 100 °C for 2 hours. After cooling the resulting deep blue solution to room temperature, it was filtered into a tube for diffusion. This process yielded black parallelepiped crystals of 3, exhibiting a distinctive copper luster, with a 74% yield.

Organic Solar Cells Based on Tin(II) Phthalocyanine (SnPc)/C60

Du, Chao, et al. Energy Procedia, 2011, 12, 519-524.

Organic solar cells (OSCs) based on tin(II) phthalocyanine (SnPc)/C60 heterojunction were prepared, and the effect of SnPc thickness on the device electrical characteristics was studied. According to the results, power conversion efficiency was 0.79% with SnPc thickness of 15 nm which has the highest J_SC and highest V_OC, with tolerable FF.
Preparation of OPV cells
· The OPV cells tested were OPV cells ITO/PEDOT:PSS (10 nm)/MoO3 (10 nm)/SnPc (x nm)/C60 (40 nm)/BPhen (10 nm)/Ag, with x equal to 6, 9, 12, 15, and 18. The devices were manufactured on indium-tin oxide (ITO) coated glass substrates with 180 nm thickness and sheet resistance of 10 /sq.
· Prior to loading into a vacuum chamber, the ITO substrates were thoroughly cleaned in ultrasonic baths with detergent, acetone, ethanol, and deionized water for 10 minutes each, followed by drying with high-purity nitrogen. The substrates underwent an O2 plasma treatment for 5 minutes before being coated with PEDOT:PSS by spin-coating.
· After this, layers of MoO3, SnPc, C60 and BPhen were followed by sequential evaporates on to the ITO substrates using an OLED-V organic multifunctional vacuum deposition system at 1-2 Å/s and 3×10^-4 Pa. Then silver was vaporised, as the cathode, at about 10 /s, at 3×10^-3 Pa.

Custom Q&A

What is the molecular formula of Phthalocyanine Tin(II)?

The molecular formula is C32H16N8Sn.

What are the synonyms for Phthalocyanine Tin(II)?

The synonyms are Phthalocyanine Tin(II), 2,11,20,29,37,38-Hexaza-39,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19,21(38),22,24,26,28,30(37),31,33,35-nonadecaene;tin(2+), [Phthalocyaninato(2-)]tin, DTXSID00424848, and tin(2+) phthalocyanine-29,31-diide.

What is the molecular weight of Phthalocyanine Tin(II)?

The molecular weight is 631.2 g/mol.

What is the parent compound of Phthalocyanine Tin(II)?

The parent compound is Phthalocyanine.

What are the component compounds of Phthalocyanine Tin(II)?

The component compounds are Phthalocyanine, Tin powder, and 31h-Phthalocyanine.

When was Phthalocyanine Tin(II) created?

It was created on May 3, 2006.

When was Phthalocyanine Tin(II) last modified?

It was last modified on October 21, 2023.

What is the IUPAC name of Phthalocyanine Tin(II)?

The IUPAC name is 2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene;tin(2+).

What is the InChI of Phthalocyanine Tin(II)?

The InChI is InChI=1S/C32H16N8.Sn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2.

What is the CAS number of Phthalocyanine Tin(II)?

The CAS number is 15304-57-1.