Tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate, min. 98%

• CAS: 59738-27-1
• Catalog Number: ACM59738271
• Category: Main Products
• Molecular Weight: 832.795g/mol
• Molecular Formula: C16H24F12N3RhSb2
• Synonyms: MFCD18827646;Tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate;59738-27-1
• IUPAC Name: acetonitrile;hexafluoroantimony(1-);1,2,3,4,5-pentamethylcyclopenta-1,3-diene;rhodium(2+)
• Canonical SMILES: CC#N.CC#N.CC#N.CC1=C([C](C(=C1C)C)C)C.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.[Rh+2]
• InChI: InChI=1S/C10H15.3C2H3N.12FH.Rh.2Sb/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;;;;;;;;;;;;;;;/h1-5H3;3*1H3;12*1H;;;/q;;;;;;;;;;;;;;;;+2;2*+5/p-12
• InChI Key: NDCQZFNTKVLFPQ-UHFFFAOYSA-B
• Application: Catalyst used for the oxidative, cross-coupling/cyclization of aryl aldimines and alkynes.; ; Catalyst used for the intermolecular hydroarylation of alkynes.; ; Catalyst useful for the Fagnou Indole/Pyrrole Synthesis.; ; Catalyst for directed C-H functionalization with enamides and isocyanates.
• Complexity: 233
• Covalently-Bonded Unit Count: 7
• Exact Mass: 832.891g/mol
• H-Bond Acceptor: 17
• Heavy Atom Count: 34
• Monoisotopic Mass: 830.891g/mol
• Topological Polar Surface Area: 71.4A^2

Custom Reviews

January 20, 2023

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Excellent acidic catalyst
In organic reactions, tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate generates stable free radical cation salts, which are used as acidic catalysts in epoxide ring-opening reactions.