4-(Trimethylsilyl)phenylboronic acid

• CAS: 17865-11-1
• Catalog Number: ACM17865111
• Category: Boronic Acids
• Molecular Weight: 194.11g/mol
• Molecular Formula: C9H15BO2Si
• Synonyms: P-(TRIMETHYLSILYL)PHENYLBORONIC ACID;4-(TRIMETHYLSILYL)PHENYLBORONIC ACID;4-TRIMETHYLSILYLBENZENEBORONIC ACID;AKOS BRN-0431;4-triemthylsilylphenylboronic acid;4-(Trimethylsilyl)phenylboronic Acid (contains varying amounts of Anhydride);p-Trimethylsilylben
• IUPAC Name: (4-trimethylsilylphenyl)boronic acid
• Canonical SMILES: B(C1=CC=C(C=C1)[Si](C)(C)C)(O)O
• InChI: InChI=1S/C9H15BO2Si/c1-13(2,3)9-6-4-8(5-7-9)10(11)12/h4-7,11-12H,1-3H3
• InChI Key: NRPZMSUGPMYBCQ-UHFFFAOYSA-N
• Complexity: 160
• Covalently-Bonded Unit Count: 1
• Exact Mass: 194.093436g/mol
• Formal Charge: 0
• H-Bond Acceptor: 2
• H-Bond Donor: 2
• Heavy Atom Count: 13
• Monoisotopic Mass: 194.093436g/mol
• Rotatable Bond Count: 2

Synthetic Use

Upstream Synthesis Route 1

• 6999-03-7

• 17865-11-1

Reference: [1] Patent: WO2010/140801, 2010, A1, . Location in patent: Page/Page column 18

Upstream Synthesis Route 2

• 5419-55-6
• 106-37-6

• 17865-11-1

Reference: [1] Patent: US6034089, 2000, A,

Downstream Synthesis Route 1

• 17865-11-1

• 67665-47-8

Reference: [1] Angewandte Chemie - International Edition, 2018, vol. 57, # 22, p. 6696 - 6700[2] Angew. Chem., 2018, vol. 130, p. 6806 - 6810,5
[3] Angewandte Chemie - International Edition, 2018, vol. 57, # 22, p. 6696 - 6700[4] Angew. Chem., 2018, vol. 130, p. 6806 - 6810,5

Downstream Synthesis Route 2

• 126-30-7
• 17865-11-1

• 574755-28-5

Reference: [1]Angewandte Chemie - International Edition,2018,vol. 57,p. 16648 - 16653
Angew. Chem.,2018,vol. 130,p. 16890 - 16895,6

Downstream Synthesis Route 3

• 18014-00-1
• 17865-11-1

• 635321-73-2

Reference: [1]Patent: WO2010/140801,2010,A1 .Location in patent: Page/Page column 18
[2]Macromolecules,2003,vol. 36,p. 2327 - 2332
[3]Organic and Biomolecular Chemistry,2003,vol. 1,p. 1609 - 1624

* For details of the synthesis route, please refer to the original source to ensure accuracy.