Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4

CAS

178879-60-2

Catalog Number

ACM178879602

Category

Rhodium series of catalysts

Molecular Weight

1900.259g/mol

Molecular Formula

C92H148N4O16Rh2S4;

MSDS COA Spec Sheet

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Specification

Synonyms

AKOS015909399; 178879-60-2; Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), AldrichCPR; MFCD04974245; TETRAKIS[(R)-(+)-N-(4-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II); TETRAKIS[(R)-(+)-N-(P-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II);

IUPAC Name

(2R)-1-(4-dodecylphenyl)sulfonylpyrrolidine-2-carboxylic acid;rhodium;

Canonical SMILES

CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.[Rh].[Rh];

InChI

InChI=1S/4C23H37NO4S.2Rh/c4*1-2-3-4-5-6-7-8-9-10-11-13-20-15-17-21(18-16-20)29(27,28)24-19-12-14-22(24)23(25)26;;/h4*15-18,22H,2-14,19H2,1H3,(H,25,26);;/t4*22-;;/m1111../s1;

InChI Key

IGTBJBHOQXYDMM-MSZWWGBCSA-N;

Application

Catalyst used for tandem asymmetric cyclopropanation/Cope rearrangement.

Catalyst used for an asymmetric [4 + 3] cycloaddition.

Complexity

1240

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Exact Mass

1898.788g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

118

Monoisotopic Mass

1898.788g/mol

Rotatable Bond Count

Topological Polar Surface Area

332A^2

January 20, 2023

Efficient asymmetric catalyst
Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II)(Rh2(R-DOSP)4) can be used as a catalyst for asymmetric [4+3] cycloaddition and has high catalytic activity.

What is molecular formula of Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4?

C92H148N4O16Rh2S4

What is the EC number of Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4?

811-767-3

What is exact mass of Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4?

1898.78831

What is chemical formula of Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4?

[C23H36NO4S]4Rh2

What is color and form of Tetrakis[(R)-(+)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(R-DOSP)4?

Green powder

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