(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

• CAS: 192139-90-5
• Catalog Number: ACM192139905-1
• Category: Main Products
• Molecular Weight: 636.21
• Molecular Formula: C31H35ClN2O2RuS
• Synonyms: Methyl-4-(1-methylethyl)benzene]-ruthenium; RuCl(p-cymene)[(S,S)-Ts-DPEN]; RuCl(p-cymene)[(R,R)-TsDPEN]; RuCl[(S,S)-Tsdpen](p-cymene)
• Melting Point: >175 °C
• Appearance: Orange brown crystalline powder
• Application: This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
• Storage: 2-8°C

Custom Q&A

What is the product name of the chemical compound with CAS number 192139-90-5?

The product name is (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II).

What are some synonyms for the chemical compound?

Some synonyms include -1,2-diphenylethanediamine(chloro), Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), RuCl(p-cymene)[(S,S)-Ts-DPEN], etc.

What is the molecular weight of the chemical compound?

The molecular weight is 631.17.

What is the chemical formula of the compound?

The chemical formula is C31H30ClN2O2RuS.

What is the melting point of the compound?

The melting point is greater than 175 °C.

In what form is the compound stored?

The compound is stored in solid form.

What is the optical activity of the compound in chloroform?

The optical activity is [α]20/D +178°, c = 0.5 in chloroform.

In which solvents is the compound soluble?

The compound is soluble in Chloroform, DCM, and Ethyl Acetate.

What is the color of the compound?

The compound is yellow to dark brown in color.

What are some uses of the compound?

The compound is used as a catalyst in asymmetric transfer hydrogenation of imines and ketones, intramolecular asymmetric reductive amination, and tandem hydroformylation/hydrogenation of terminal olefins. It is also a reactant involved in studies of the thermal decomposition of areneruthenium chiral amido-amine alkyl complexes.