RuCl2[(R)-xylbinap][(R)-daipen]

• CAS: 220114-32-9
• Catalog Number: ACM220114329
• Category: Other Products
• Molecular Weight: 1221.30
• Molecular Formula: C71H74Cl2N2O2P2Ru
• Application: Highly active catalyst for hydrogenation of simple ketones giving high enantioselectivity when sterically unsymmetrical ketones such as acetophenone, heteroaryl ketones, benzophenones, cyclopropyl ketones, and cyclohexyl ketones are substrates. Ee's are enhanced with XylBINAP relative to BINAP. The otherwise poorly bonded ketone is held in the transition state by hydrogen bonding to the protic bidentate amine.; ; Carbonyl groups are selectively reduced even when olefins exist in the same molecule.; ; In the presence of strong base, and catalyst, simple ketones, having substituents at the α-position, may be induced to undergo dynamic kinectic resolution during their hydrogenation to produce two chiral carbon centers in high yield.
• Storage: 2-8°C

Custom Q&A

What is the molecular formula of RuCl2[(R)-xylbinap][(R)-daipen]?

The molecular formula is C71H74Cl2N2O2P2Ru.

What is the molecular weight of RuCl2[(R)-xylbinap][(R)-daipen]?

The molecular weight is 1221.3 g/mol.

What is the IUPAC name of RuCl2[(R)-xylbinap][(R)-daipen]?

The IUPAC name is [1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine;dichlororuthenium.

What is the InChI of RuCl2[(R)-xylbinap][(R)-daipen]?

The InChI is InChI=1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/q;;;;+2/p-2.

What is the molecular weight of RuCl2[(S)-xylbinap][(S)-daipen]?

The molecular weight of RuCl2[(S)-xylbinap][(S)-daipen] is not mentioned in the reference.

What is the CAS number of RuCl2[(R)-xylbinap][(R)-daipen]?

The CAS number is 220114-01-2.

How many hydrogen bond donor atoms are there in RuCl2[(R)-xylbinap][(R)-daipen]?

There are 2 hydrogen bond donor atoms in RuCl2[(R)-xylbinap][(R)-daipen].

How many hydrogen bond acceptor atoms are there in RuCl2[(R)-xylbinap][(R)-daipen]?

There are 4 hydrogen bond acceptor atoms in RuCl2[(R)-xylbinap][(R)-daipen].

How many rotatable bonds are there in RuCl2[(R)-xylbinap][(R)-daipen]?

There are 13 rotatable bonds in RuCl2[(R)-xylbinap][(R)-daipen].

What is the topological polar surface area of RuCl2[(R)-xylbinap][(R)-daipen]?

The topological polar surface area is 70.5?^2 in RuCl2[(R)-xylbinap][(R)-daipen].