(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%

• CAS: 56977-92-5
• Catalog Number: ACM56977925
• Category: Rhodium series of catalysts
• Molecular Weight: 756.371g/mol
• Molecular Formula: C36H40BF4O2P2Rh-
• Synonyms: DTXSID10448656; 56977-92-5; SC-67687; (R,R)-(-)-1,2-bis[(o-methoxyphenyl)(phenyl)phosphino]ethane (1,5-cyclooctadiene) rhodium (I) tetrafluroborate; (1Z,5Z)-cycloocta-1,5-diene,(R)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane,rhodium,tetrafluoroborate; (R,R)-(-)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHI; BP-12198
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;(R)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane;rhodium;tetrafluoroborate
• Canonical SMILES: [B-](F)(F)(F)F.COC1=CC=CC=C1P(CCP(C2=CC=CC=C2)C3=CC=CC=C3OC)C4=CC=CC=C4.C1CC=CCCC=C1.[Rh]
• InChI: InChI=1S/C28H28O2P2.C8H12.BF4.Rh/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h3-20H,21-22H2,1-2H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t31-,32-;;;/m1.../s1
• InChI Key: DCGUTTVLWMBBAX-PFAWBQHYSA-N
• Application: Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.; ; Efficient catalyst for the asymmetric reduction of enol acetates to esters.; ; Catalyst used to prepare chiral 2-substituted succinic acid derivatives.
• Complexity: 563
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 2
• Defined Bond Stereocenter Count: 2
• Exact Mass: 756.159g/mol
• Formal Charge: -1
• H-Bond Acceptor: 7
• Heavy Atom Count: 46
• Monoisotopic Mass: 756.159g/mol
• Rotatable Bond Count: 9
• Topological Polar Surface Area: 18.5A^2

Custom Reviews

January 20, 2023

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High reactivity enantioselective catalyst
In drug synthesis, (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can catalyze the asymmetric hydrogenation of substituted dehydroalanine to N- protected amino acids.

Custom Q&A

What is color and form of (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

Orange crystalline powder

What is chemical formula of (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

[(C28H28O2P2)(C8H12Rh]+BF4-

What is molecular weight of (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(p(R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

756.36

What is the EC number of (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

688-900-5

What is the heavy atom count of (R,R)-(-)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

46