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Structure

(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol

CAS
65283-60-5
Catalog Number
ACM65283605
Category
Bromine Series
Molecular Weight
444.122g/mol
Molecular Formula
C20H12Br2O2;

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Specification

Synonyms
BCP10042; TRA0071215; FT-0756408; I14-3958; ACN-036127; 6,6 inverted exclamation marka-Dibromo-1,1 inverted exclamation marka-bi-2-naphthol; (S)-(+)-6,6'-DIBROMO-1,1'-BI-NAPHTHOL; A115490; (R)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL; [1,1'-Binaphthalene]-2,2'-diol,6,6'-dibromo-;
IUPAC Name
6-bromo-1-(6-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol;
Canonical SMILES
C1=CC2=C(C=CC(=C2C3=C(C=CC4=C3C=CC(=C4)Br)O)O)C=C1Br;
InChI
InChI=1S/C20H12Br2O2/c21-13-3-5-15-11(9-13)1-7-17(23)19(15)20-16-6-4-14(22)10-12(16)2-8-18(20)24/h1-10,23-24H;
InChI Key
OORIFUHRGQKYEV-UHFFFAOYSA-N;
Application
Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker and Mannich-type reactions.

Ligand used for titanium-catalyzed enantioselective Friedel-Crafts reactions.
Complexity
405
Covalently-Bonded Unit Count
1
Exact Mass
443.918g/mol
H-Bond Acceptor
2
H-Bond Donor
2
Heavy Atom Count
24
Monoisotopic Mass
441.92g/mol
NSC Number
9772
Rotatable Bond Count
1
Topological Polar Surface Area
40.5A^2
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