(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl

• CAS: 145964-33-6
• Catalog Number: ACM145964336
• Category: Other Products
• Molecular Weight: 468.536g/mol
• Molecular Formula: C33H25OP
• IUPAC Name: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
• Canonical SMILES: COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6
• InChI: InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3
• InChI Key: KRWTWSSMURUMDE-UHFFFAOYSA-N
• Application: 1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols.; ; 2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters.; ; 3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes.; ; 4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins.; ; 5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction.
• Complexity: 634
• Covalently-Bonded Unit Count: 1
• Exact Mass: 468.164g/mol
• H-Bond Acceptor: 1
• Heavy Atom Count: 35
• Monoisotopic Mass: 468.164g/mol
• Rotatable Bond Count: 5
• Topological Polar Surface Area: 9.2A^2