Potassium Trimethylsilanolate

• CAS: 10519-96-7
• Catalog Number: ACM10519967
• Category: Other Organosilicon
• Molecular Weight: 128.29 g/mol
• Molecular Formula: C3H9KOSi
• Synonyms: Trimethyl-Silapotassiumsalt; Trimethylsilal Potassium Salt; Potassium Trimethylsilalate, Tech., 90 %; Trimethylsiloxypotassium; Potassium Trimethylsilalate,2M In Tetrahydrofuran; (Potassiooxy)Trimethylsilane; (Trimethylsilyloxy) Potassium; Silal, 1,1,1-Trimethyl-, Potassium Salt (1:1); Nsc 408673; Trimethylsiloxypotassium; Silal, Trimethyl-, Potassium Salt; 5-Chloro-1H-Indole-2-Carboxylic Acid; Potassium Trimethylsilalate; Nsc 408673; Trimethylsiloxypotassium; Silal, Trimethyl-, Potassium Salt
• IUPAC Name: potassium;trimethyl(oxido)silane
• Canonical SMILES: C[Si](C)(C)[O-].[K+]
• InChI Key: LBKJNHPKYFYCLL-UHFFFAOYSA-N
• Boiling Point: 135-138 °C
• Melting Point: 135-138 °C
• Density: 0.91 g/mL(25 °C,lit.)
• Appearance: White to off-white crystalline powder, powder or lumps
• Application: Potassium Trimethylsilanolate is a versatile reagent with several important applications in chemical synthesis It serves as an effective agent in the hydrolysis of nitriles to produce primary amides and facilitates the conversion of esters to carboxylic acids Additionally it can transform dialkyl phosphonates into their corresponding monoalkyl phosphonates This compound is also utilized in the synthesis of E-alkenes and nitrocefin Beyond these applications Potassium Trimethylsilanolate acts as a coupling promoter in the cross-coupling reactions of aliphatic alkynylsilanols with aryl iodides demonstrating its valuable role in advancing complex organic reactions
• Storage: Store in a tightly closed container and in a cool, dry, well-ventilated place.
• EC Number: 234-062-7
• Exact Mass: 128.00600
• Hazard Statements: H314
• MDL Number: MFCD00013421
• Packaging: 10 g; 100 g
• Packing Group: III
• Precautionary Statements: P260; P264; P280; P301+P330+P331; P303+P361+P353; P304+P340+P310; P305+P351+P338+P310; P363; P405; P501
• PubChem ID: 23668039
• Safety Description: 26-36/37/39-45
• Signal Word: Danger

Custom Q&A

What is the molecular formula of potassium trimethylsilanolate?

The molecular formula is C3H9KOSi.

What is the molecular weight of potassium trimethylsilanolate?

The molecular weight is 128.29 g/mol.

What are some synonyms for potassium trimethylsilanolate?

Some synonyms include Trimethylsiloxypotassium and potassiumtrimethylsilanolate.

When was potassium trimethylsilanolate created in the database?

It was created on February 5, 2008.

What is the IUPAC name of potassium trimethylsilanolate?

The IUPAC name is potassium;trimethyl(oxido)silane.

What is the Canonical SMILES for potassium trimethylsilanolate?

The Canonical SMILES is C[Si](C)(C)[O-].[K+].

What is the CAS number for potassium trimethylsilanolate?

The CAS number is 10519-96-7.

How many hydrogen bond acceptor counts does potassium trimethylsilanolate have?

It has 1 hydrogen bond acceptor count.

What is the exact mass of potassium trimethylsilanolate?

The exact mass is 128.00597293 g/mol.

Is the compound canonicalized?

Yes, the compound is canonicalized.

Synthetic Use

Upstream Synthesis Route 1

• 107-46-0

• 10519-96-7

Reference: [1] C. A., 1949, p. 7500

Upstream Synthesis Route 2

• 1450-14-2

• 10519-96-7

Reference: [1] Chemische Berichte, 1993, vol. 126, # 2, p. 305 - 318

Upstream Synthesis Route 3

• 1450-14-2

• 10519-96-7

Reference: [1]Chemische Berichte,1993,vol. 126,p. 305 - 318

Downstream Synthesis Route 1

• 10519-96-7
• 768-33-2

• 14920-92-4

Reference: [1] Patent: CN107235996, 2017, A, . Location in patent: Paragraph 0023; 0024

* For details of the synthesis route, please refer to the original source to ensure accuracy.