Poly(vinyl ethyl ether)

• CAS: 25104-37-4
• Catalog Number: ACM25104374-1
• Category: Polymer/Macromolecule
• Molecular Weight: 72.11g/mol
• Molecular Formula: CH2=CHOCH2CH3;C4H8O;C4H8O
• Description: Vinyl ethyl ether appears as a clear colorless low-boiling liquid (35-36°C) with an ether-like odor. Flash point below -50°F. May polymerize exothermically if heated or contaminated. If polymerization takes place inside a container, the container may rupture violently. Less dense than water and slightly soluble in water. Hence floats on water. Vapors are heavier than air.;Liquid;COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.
• IUPAC Name: ethenoxyethane
• Canonical SMILES: CCOC=C
• InChI: InChI=1S/C4H8O/c1-3-5-4-2/h3H,1,4H2,2H3
• InChI Key: FJKIXWOMBXYWOQ-UHFFFAOYSA-N
• Boiling Point: 96 °F at 760 mm Hg (USCG, 1999);35.5 °C;35.5 °C;36 °C
• Melting Point: -175 °F (USCG, 1999);-115.8 °C;-115.8 °C;-115 °C
• Flash Point: less than -50 °F (USCG, 1999);< -50 °F (< -46 °C) /closed cup/
• Density: 0.7589 at 68 °F (USCG, 1999);0.7589 at 20 °C;Relative density (water = 1): 0.8
• Solubility: In water, 7800 mg/L at 25 °C;In water, 10000 mg/L at 37 °C;Slightly soluble in carbon tetrachloride; soluble in ethanol; miscible in ether;Solubility in water, g/l at 15 °C: 8.3 (slightly soluble)
• Appearance: Slab
• Alpha Sort: Poly(vinyl ethyl ether)
• Autoignition Temperature: 395 °F (USCG, 1999);202 °C
• Color/Form: Colorless liquid;Ether-like odor
• Complexity: 24.8
• Covalently-Bonded Unit Count: 1
• Decomposition: Hazardous decomposition products formed under fire conditions. - Carbon oxides;When heated to decomposition it emits acrid smoke and irritating fumes.
• EC Number: 203-718-4
• Exact Mass: 72.057515g/mol
• Formal Charge: 0
• H-Bond Acceptor: 1
• H-Bond Donor: 0
• Heat of Vaporization: 26.2 kJ/mol at 35.5 °C
• Heavy Atom Count: 5
• ICSC Number: 1261
• LogP: 1.04 (LogP);log Kow = 1.04;1.04
• Monoisotopic Mass: 72.057515g/mol
• NSC Number: 8405
• Other Experimental: A very dangerous fire and explosion hazard when exposed to heat or flame; can react vigorously with oxidizing materials.;May polymerize exothermically if heated or contaminated. If polymerization takes place inside a container, the container may rupture violently.;Henry's Law constant = 6.3X10-3 atm-cu m/mole at 25 °C (estimated from vapor pressure and water solubility);Hydroxyl radical reaction rate constant = 7.79X10-11 cu cm/molec-sec at 25 °C;Nitrate radical reaction rate constant = 1.40X10-12 cu cm/molec-sec at 25 °C;Ozone reaction rate constant = 2.0X10-16 cu cm/molec-sec at 25 °C
• Refractive Index: Index of refraction: 1.3767 at 20 °C
• Rotatable Bond Count: 2
• RTECS Number: KO0710000
• Stability: Stable under recommended storage conditions. Contains the following stabilizer(s): N,N-Diethylaniline (0.1 %).
• UNII: 6235C9592H
• UN Number: 1302;1302;1302;1302
• Vapor Density: 2.5 (Air = 1);Relative vapor density (air = 1): 2.5
• Vapor Pressure: 510.98 mmHg;515 mm Hg at 25 °C;Vapor pressure, kPa at 20 °C: 56
• Viscosity: 0.3 mm2/s
• XLogP3: 1