Nonanol

• CAS: 143-08-8
• Catalog Number: ACM143088
• Category: Alcohols; Fatty Alcohols
• Molecular Weight: 144.20
• Molecular Formula: C9H20O
• Description: Nonanol appears as colorless liquid with a rose or fruity odor. Floats on water. Freezing point 23°F. (USCG, 1999);Liquid;Liquid;Liquid;colourless liquid/rose-citrus odour
• Synonyms: Pelargonic alcohol
• IUPAC Name: nonan-1-ol
• Canonical SMILES: CCCCCCCCCO
• InChI: InChI=1S/C9H20O/c1-2-3-4-5-6-7-8-9-10/h10H,2-9H2,1H3
• InChI Key: ZWRUINPWMLAQRD-UHFFFAOYSA-N
• Boiling Point: 215 °C (lit.)
• Melting Point: −8-−6 °C (lit.)
• Flash Point: 165 °F (USCG, 1999);165 °F
• Density: 0.827 at 68 °F (USCG, 1999);d204 0.83;0.8279 at 20 °C/4 °C;0.824-0.830
• Solubility: 9.71e-04 M;0.14 mg/mL at 25 °C;Miscible with alcohol, ether;Soluble in ethanol, ether; very soluble in carbon tetrachloride;In water, 140 mg/L at 25 °C;0.14 mg/mL at 25 °C;miscible with alcohol, chloroform, ether; insoluble in water;1 ml in 3 ml 60% alcohol gives clear soln (in ethanol)
• Appearance: Liquid
• Storage: Room temperature
• Alcohol: Nonanol
• CNo.Chain: C9:0
• Color/Form: Colorless to yellowish liquid
• Complexity: 52.7
• Covalently-Bonded Unit Count: 1
• Decomposition: When heated to decomposition it emits acid smoke and irritating fumes.
• EC Number: 205-583-7;228-205-2;249-048-6
• Exact Mass: 144.151415g/mol
• Formal Charge: 0
• Hazard Statements: H302
• H-Bond Acceptor: 1
• H-Bond Donor: 1
• Heat of Vaporization: 76.86 kJ/mol at 25 °C
• Heavy Atom Count: 10
• LogP: 3.77 (LogP);3.77;log Kow = 3.77;3.77
• Monoisotopic Mass: 144.151415g/mol
• NSC Number: 5521
• Odor: Floral odor;Odor of citronella oil
• Other Experimental: BP: 215 °C at 760 mm Hg; 107.5 °C at 15 mm Hg; 95.6 °C at 7.5 mm Hg;Henry's Law constant = 3.1X10-5 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 1.4X10-11 cu cm/molec-sec at 25 °C (est)
• Physical State: Liquid
• Refractive Index: n20D 1.4330;Index of refraction = 1.4338 at 20 °C/D;1.431-1.435
• RIDADR: NONH for all modes of transport
• Rotatable Bond Count: 7
• Symbol: GHS07
• UNII: NGK73Q6XMC
• UN Number: 3082
• Vapor Pressure: 0.02 mmHg;0.0227 mm Hg at 25 °C (est)
• Viscosity: 11.7 centapoise at 20 °C
• XLogP3: 4.3

Synthetic Use

Upstream Synthesis Route 1

• 31502-19-9

• 3937-56-2
• 4469-84-5
• 61448-29-1
• 143-08-8

Reference: [1] Journal of the American Chemical Society, 2013, vol. 135, # 46, p. 17393 - 17400

Upstream Synthesis Route 2

• 4900-30-5

• 3937-56-2
• 13038-21-6
• 63768-13-8
• 143-08-8

Reference: [1] Tetrahedron Letters, 2001, vol. 42, # 5, p. 785 - 787

Upstream Synthesis Route 3

• 123-29-5

• 143-08-8

Reference: #N/A

Downstream Synthesis Route 1

• 143-08-8

• 693-58-3

Reference: [1] Journal of Organic Chemistry, 1980, vol. 45, # 9, p. 1638 - 1639

Downstream Synthesis Route 2

• 636-53-3
• 143-08-8

• 4654-19-7

Reference: [1]Journal of the American Chemical Society,2014,vol. 136,p. 7869 - 7872

Downstream Synthesis Route 3

• 143-08-8

• 124-19-6

Reference: [1]Zhurnal Fizicheskoj Khimii,1953,vol. 27,p. 790
Chem.Abstr.,1955,p. 2828

* For details of the synthesis route, please refer to the original source to ensure accuracy.