[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]

• CAS: 199541-17-8
• Catalog Number: ACM199541178
• Category: Ruthenium series catalysts
• Molecular Weight: 1673.882g/mol
• Molecular Formula: C90H75Cl5NP4Ru2+
• Synonyms: (S)-[(RuCl(BINAP))2( -Cl)3][NH2Me2]; Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]; (S)-[(RUCL(BINAP))2(MU-CL)3][NH2ME2]; [NH2ME2][[RUCL((S)-BINAP)]2(MU-CL)3]; (R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]; Dimethylammonium dichlorotri(|I-chloro)bis[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]diruthenate(II); Dimethylammonium dichlorotri(|I-chloro)bis[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]diruthenate(II); [NH2ME2][[RUCL((R)-BINAP)]2(MU-CL)3]; (R)-[(RUCL(BINAP))2(MU-CL)3[NH2ME2]]
• IUPAC Name: [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride
• Canonical SMILES: CNC.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl.[Cl-].[ClH+][Ru-]([ClH+])[ClH+].[Ru]
• InChI: InChI=1S/2C44H32P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;5*1H;;/q;;;;;;;;;+2/p-1
• InChI Key: NVDGOPZSESFSJS-UHFFFAOYSA-M
• Application: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.; ; Useful ligand in asymmetric Heck processes.; ; 3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones.; ; 4. Ligand employed in rhodium-catalyzed 1,4-additions to enones.; ; 5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.; ; 6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.; ; 7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes.; ; 8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.; ; 9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.; ; 10. Ligand employed in palladium-catalyzed synthesis of chiral allenes.; ; 11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.; ; 12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.; ; 13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.; ; 14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.; ; 15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
• Storage: 2-8°C
• Complexity: 809
• Covalently-Bonded Unit Count: 7
• Exact Mass: 1676.136g/mol
• Formal Charge: 1
• H-Bond Acceptor: 3
• H-Bond Donor: 5
• Heavy Atom Count: 102
• Monoisotopic Mass: 1672.138g/mol
• Rotatable Bond Count: 14
• Topological Polar Surface Area: 12A^2