N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite((S)-SIPHOS)

• CAS: 443965-10-4
• Catalog Number: ACM443965104
• Category: Other Products
• Molecular Weight: 325.348g/mol
• Molecular Formula: C19H20NO2P
• Synonyms: N-Dimethyl-[(R)-1,1 inverted exclamation marka-spirobiindane-7,7 inverted exclamation marka-diyl]phosphoramidite; MFCD08459340; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1 inverted exclamation marka,7 inverted exclamation marka-fg][1,3,2]dioxaphosphocin-5-dimethylamine; (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1\',7\'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE; AB1005806; CS-0062402; AKOS015950893; SCHEMBL13324483; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1,7-fg][1,3,2]dioxaphosphocin-5-dimethylamine,N-Dimethyl-[(R)-1,1-spirobiindane-7,7-diyl]phosphoramidite
• IUPAC Name: N,N-dimethyl-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
• Canonical SMILES: CN(C)P1OC2=CC=CC3=C2C4(CC3)CCC5=C4C(=CC=C5)O1
• InChI: InChI=1S/C19H20NO2P/c1-20(2)23-21-15-7-3-5-13-9-11-19(17(13)15)12-10-14-6-4-8-16(22-23)18(14)19/h3-8H,9-12H2,1-2H3
• InChI Key: RIDZEECIONITMW-UHFFFAOYSA-N
• Application: Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.; ; Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.; ; Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.; ; Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.; ; Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.; ; Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
• Storage: -20°C
• Complexity: 432
• Covalently-Bonded Unit Count: 1
• Exact Mass: 325.123g/mol
• H-Bond Acceptor: 3
• Heavy Atom Count: 23
• Monoisotopic Mass: 325.123g/mol
• Rotatable Bond Count: 1
• Topological Polar Surface Area: 21.7A^2