Lithium Chloride (2.3% in Tetrahydrofuran, ca. 0.5mol/L)

CAS

7447-41-8

Catalog Number

ACM7447418

Category

Metal & Ceramic Materials

Molecular Weight

42.39g/mol

Molecular Formula

LiCl;LiCl;ClLi;

MSDS COA Spec Sheet

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Specification

Synonyms

Chlorku litu; Lithium Cholride; SC-46832; RTR-024082; Lithium chloride, ACS reagent; Lithium chloride battery grade; NCGC00015607-04; Lithium chloride, 99%, extra pure; Lithiumchlorid; CTK3J2462;

IUPAC Name

lithium;chloride;

Canonical SMILES

[Li+].[Cl-];

InChI

InChI=1S/ClH.Li/h1H;/q;+1/p-1;

InChI Key

KWGKDLIKAYFUFQ-UHFFFAOYSA-M;

Melting Point

1121 ° F (NTP, 1992);610 deg C;613 °C;

Density

2.068 at 77 ° F (NTP, 1992);2.07 g/cu cm;Relative density (water = 1): 2.1;

Solubility

Very soluble (NTP, 1992);84.5 g/100 g water at 25 deg C; soluble in ethanol, acetone, pyridine;25.10 G SOL IN 100 CC ALC @ 30 DEG C; 42.36 G SOL IN 100 CC METHANOL @ 25 DEG C; 4.11 G SOL IN 100 CC ACETONE @ 25 DEG C; 0.538 G SOL IN 100 CC AMMONIUM HYDROXIDE @ 33.9 DEG C;Very soluble in water alcohols, ether, pyridine, nitrobenzene;In water (g/100g): 83.2 at 20 deg C, 89.8 at 40 deg C, 98.4 at 60 deg C, 111.9 at 80 deg C, 128.3 at 100 deg C; in ethanol: 2.5 g/100g at 25 deg C; in methanol: 17 g/100g at 25 deg C;Solubility in water, g/100ml: 76.9;

Application

Lithium chloride is used as an antidepressant, especially in the treatment of manic depression and bipolar disorders.

Storage

2-8°C

Color/Form

Deliquescent, cubic crystals, granules or crystalline powder;White cubic crystals or powder; hygroscopic;

Complexity

Corrosivity

May become corrosive upon contact with water or moist surfaces;

Covalently-Bonded Unit Count

Decomposition

When heated to decomposition it emits toxic fumes of /chloride/.;

EC Number

231-212-3

Exact Mass

41.985g/mol

H-Bond Acceptor

Heavy Atom Count

ICSC Number

0711

Monoisotopic Mass

41.985g/mol

NSC Number

327172

Octanol Water Partition Coefficient

-2.7;

Other Experimental

One of the most hygroscopic salts known;Standard molar enthalpy of formation at 298.15 K: -408.6 kJ/mol; molar heat capacity at constant pressure and 298.15 K: 48.0 J/mol K;Enthalpy of fusion: 19.9 kJ/mol;

Aqueous solution: neutral or slightly alkaline;

Physical Description

LITHIUM CHLORIDE is a colorless crystals or powder. Low toxicity.;DryPowder, Liquid; Liquid; PelletsLargeCrystals, WetSolid;COLOURLESS-TO-WHITE HYGROSCOPIC AND DELIQUESCENT CRYSTALS OR POWDER.;

RTECS Number

OJ5950000

Topological Polar Surface Area

0A^2

UNII

G4962QA067

Vapor Pressure

1 mm Hg at 547 deg C;