Hexamethyldistannane

• CAS: 661-69-8
• Catalog Number: ACM661698
• Category: Organic Tin
• Molecular Weight: 327.6g/mol
• Molecular Formula: C6H18Sn2
• Synonyms: HEXAMETHYLDISTANNANE;HEXAMETHYLDITIN;HEXAMETHYLDITIN(IV);((CH3)3Sn)2;1,1,1,2,2,2-Hexamethyldistannane;1,1,1,2,2,2-Hexamethyl-distannane;Distannane, hexamethyl-;hexamethyl-distannan
• Canonical SMILES: C[Sn](C)C.C[Sn](C)C
• InChI: InChI=1S/6CH3.2Sn/h6*1H3
• InChI Key: CCRMAATUKBYMPA-UHFFFAOYSA-N
• Application: Hexamethyldistannane serves as a versatile reagent in organic synthesis, primarily utilized for preparing various aryl tin compounds. It is pivotal in microwave-assisted Stille cross-coupling with halo pyridines and in the copper-mediated O-arylation of phenols. Functioning as a raw material, it facilitates the production of other compounds through its reaction with 1,3-dienes to produce dimerization-double-stannation adducts with notable regio- and stereo-selectivity, aided by a catalytic quantity of bis(dibenzylideneacetone)palladium. Furthermore, it exhibits high yield in synthesizing allytrimethylstannanes from a wide array of allylic compounds, such as allyl acetates and allyl halides, when palladium complexes are present. Hexamethyldistannane also facilitates direct stannylation of halopyridines and bipyridines via Pd catalysis and can be added to 1-alkynes to form (Z)-1,2-Bis(Trimethylstannyl)-1-Alkenes in the presence of a palladium complex.
• Complexity: 22
• Covalently-Bonded Unit Count: 2
• EC Number: 211-549-2
• Exact Mass: 327.94466g/mol
• Formal Charge: 0
• H-Bond Acceptor: 0
• H-Bond Donor: 0
• Heavy Atom Count: 8
• Monoisotopic Mass: 329.94525g/mol
• NSC Number: 227328
• Rotatable Bond Count: 0

Custom Q&A

What is the molecular formula of Hexamethyldistannane?

The molecular formula of Hexamethyldistannane is C6H18Sn2.

What is the molecular weight of Hexamethyldistannane?

The molecular weight of Hexamethyldistannane is 327.63 g/mol.

What is the parent compound of Hexamethyldistannane?

The parent compound of Hexamethyldistannane is Trimethyltin (CID 5358116).

What is the InChI of Hexamethyldistannane?

The InChI of Hexamethyldistannane is InChI=1S/6CH3.2Sn/h6*1H3.

What is the InChIKey of Hexamethyldistannane?

The InChIKey of Hexamethyldistannane is CCRMAATUKBYMPA-UHFFFAOYSA-N.

What is the Canonical SMILES of Hexamethyldistannane?

The Canonical SMILES of Hexamethyldistannane is C[Sn](C)C.C[Sn](C)C.

What is the CAS number of Hexamethyldistannane?

The CAS number of Hexamethyldistannane is 661-69-8.

What is the European Community (EC) number of Hexamethyldistannane?

The European Community (EC) number of Hexamethyldistannane is 211-549-2.

What is the UNII of Hexamethyldistannane?

The UNII of Hexamethyldistannane is DSR4SPH97E.

What is the complexity of Hexamethyldistannane?

The complexity of Hexamethyldistannane is 22.