Structure

Fmoc-hArg(Pbf)-OH

CAS
1159680-21-3
Catalog Number
ACM1159680213
Category
Amino Acids
Molecular Weight
662.8
Molecular Formula
C35H42N4O7S

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Specification

Description
Fmoc-homoArg(Pbf)-OH is a useful tool for the introduction of homoarginine during Fmoc SPPS. It can be used in exactly the same manner as Fmoc-Arg(Pbf)-OH.
Synonyms
Fmoc-hArg(Pbf)-OH, N-α-Fmoc-N G-(2,2,4,6,7-pentamethyldihydrobenzofuran-5-sulfonyl)-L-homoarginine
IUPAC Name
(2R)-6-[[amino-[(2,2,4,6,7-pentamethyl-3H-1-benzofuran-5-yl)sulfonylamino]methylidene]amino]-2-(4b,8a,9,9a-tetrahydro-4aH-fluoren-9-ylmethoxycarbonylamino)hexanoic acid
Canonical SMILES
CC1=C(C(=C(C2=C1OC(C2)(C)C)C)S(=O)(=O)NC(=NCCCCC(C(=O)O)NC(=O)OCC3C4C=CC=CC4C5C3C=CC=C5)N)C
InChI
1S/C35H46N4O7S/c1-20-21(2)31(22(3)27-18-35(4,5)46-30(20)27)47(43,44)39-33(36)37-17-11-10-16-29(32(40)41)38-34(42)45-19-28-25-14-8-6-12-23(25)24-13-7-9-15-26(24)28/h6-9,12-15,23-26,28-29H,10-11,16-19H2,1-5H3,(H,38,42)(H,40,41)(H3,36,37,39)/t23?,24?,25?,26?,28?,29-/m1/s1
InChI Key
CNVDMZSITINVNW-XHQXOEBXSA-N
Application
Peptide synthesis.
Assay
≥95.0% (HPLC)
≥97% (TLC)
Exact Mass
662.277
Form
powder
Functional Group
Fmoc
LogP
7.6434
PSA
175.29
Quality Level
200
Reaction Suitability
reaction type: Fmoc solid-phase peptide synthesis
Storage Temperature
15-25℃
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