disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate

• CAS: 6441-91-4
• Catalog Number: ACM6441914
• Category: Acid Dyes
• Molecular Weight: 512.37
• Molecular Formula: C16H10N4Na2O9S2
• Description: The synthesis pathway for 2-Naphthalenesulfonic acid, 6-amino-4-hydroxy-5-[(4-nitro-2-sulfophenyl)azo]-, disodium salt involves the diazotization of 4-nitro-2-sulfophenylamine followed by coupling with 6-amino-4-hydroxy-2-naphthalenesulfonic acid. The resulting product is then converted to the disodium salt form.
• Synonyms: Acid Violet 1;Acid violet1 (C.I. 17025)
• IUPAC Name: disodium;6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate
• Canonical SMILES: C1=CC(=C(C2=C(C=C(C=C21)S(=O)(=O)[O-])O)N=NC3=C(C=C(C=C3)[N+](=O)[O-])S(=O)(=O)[O-])N.[Na+].[Na+]
• InChI: InChI=1S/C16H12N4O9S2.2Na/c17-11-3-1-8-5-10(30(24,25)26)7-13(21)15(8)16(11)19-18-12-4-2-9(20(22)23)6-14(12)31(27,28)29;;/h1-7,21H,17H2,(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2
• InChI Key: ARZVLGVDYAMAFX-UHFFFAOYSA-L
• Appearance: Powder
• Storage: Store at 2-8 ℃
• Complexity: 882
• EC Number: 229-230-1
• Exact Mass: 511.968445
• Heavy Atom Count: 33
• Hydrogen Bond Acceptor Count: 12
• Hydrogen Bond Donor Count: 2
• Monoisotopic Mass: 511.96845882
• PSA: 247.95
• Rotatable Bond Count: 2
• Topological Polar Surface Area: 248Å2
• XLogP3: 5.5254

Case Study

Study on the Adsorption of Acid Violet 1 by Polymer Microspheres

Monika Wawrzkiewicz, et al. Molecules. 2020, 25(22), 5247.

Acid violet 1 is a synthetic, water-soluble dye that belongs to the class of dyes known as triarylmethane dyes. A copolymer microsphere of divinylbenzene copolymer with glycidyl methacrylate functionalized with triethylenetetramine (DVB-co-GMA-TETA) resin has been synthesized for the removal of acid dyes (e.g., Acid violet 1). The adsorption capacity of this adsorbent for acid violet 1 can reach 172 mg/g.
Adsorption mechanism of acid violet 1
· The dye adsorption on DVB-co-GMA-TETA probably takes place as a result of physisorption and chemical interactions.
· The electrostatic interaction (ionic bond) between the positively charged functional groups of the resin and the negatively charged sulfonic groups of the dyes are created.
· Additionally, hydrogen bonds and π-π interactions between the aromatic rings of benzene present in the resin matrix and dyes may occur.

Adsorption and Advanced Oxidation Removal Strategies for Acid Violet 1

Wawrzkiewicz M, et al. Processes, 2021, 9(11), 1911.

Acid violet 1 is an azo dye that degrades into toxic aromatic amines in the environment. Adsorption and advanced oxidation process (AOP) have proven to be two effective techniques for the removal of acid violet from aqueous solutions.
· Adsorption removal for acid violet 1
A strong alkaline anion exchanger with a macroporous structure was used to perform adsorption and desorption tests on acid violet 1 at room temperature using intermittent technology. Dye removal efficiencies of more than 99% can be achieved after 240 minutes using anion exchange resin in 100-500 mg/L solutions.
· Advanced oxidation process for acid violet 1
Hydrogen peroxide (H2O2) or peracetic acid (PAA) was used as the oxidant to evaluate the decolorization and mineralization effects of the AOP process on acid violet under different oxidation conditions. Compared with H2O2, Fenton reaction, PAA/Fe2+ and PAA/Fe2+/sunlight systems are more effective for the decolorization and mineralization of acid violet 1 solution.

Custom Q&A

What is the PubChem CID for Acid Violet 1?

The PubChem CID for Acid Violet 1 is 135764771.

What is the molecular formula of Acid Violet 1?

The molecular formula of Acid Violet 1 is C16H10N4Na2O9S2.

What is the synonyms for Acid Violet 1?

The synonyms for Acid Violet 1 include C.I. Acid Violet 1, Acid Fast Violet R, Fenazo Violet T, and more.

What is the molecular weight of Acid Violet 1?

The molecular weight of Acid Violet 1 is 512.4 g/mol.

When was Acid Violet 1 created and last modified according to the reference?

Acid Violet 1 was created on 2019-01-17 and last modified on 2023-12-02.

What is the IUPAC name of Acid Violet 1?

The IUPAC name of Acid Violet 1 is disodium; 6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate.

What is the Canonical SMILES of Acid Violet 1?

The Canonical SMILES of Acid Violet 1 is C1=CC(=C(C2=C(C=C(C=C21)S(=O)(=O)[O-])O)N=NC3=C(C=C(C=C3)[N+](=O)[O-])S(=O)(=O)[O-])N.[Na+].[Na+].

How many hydrogen bond donor counts does Acid Violet 1 have?

Acid Violet 1 has 2 hydrogen bond donor counts.

What is the hydrogen bond acceptor count of Acid Violet 1?

Acid Violet 1 has 12 hydrogen bond acceptor counts.

How many defined atom stereocenter counts does Acid Violet 1 have?

Acid Violet 1 has 0 defined atom stereocenter counts.

What is the molecular formula of disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

The molecular formula is C16H10N4Na2O9S2.

What is the molecular weight of disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

The molecular weight is 512.4 g/mol.

What are some synonyms for disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

Some synonyms include Acid Violet 1, C.I. Acid Violet 1, Acid Fast Violet R, and Fenazo Violet T.

When was disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate created?

It was created on January 17, 2019.

What is the IUPAC name of disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

The IUPAC name is disodium;6-amino-4-hydroxy-5-[(4-nitro-2-sulfonatophenyl)diazenyl]naphthalene-2-sulfonate.

What is the Canonical SMILES representation of disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

The Canonical SMILES is C1=CC(=C(C2=C(C=C(C=C21)S(=O)(=O)[O-])O)N=NC3=C(C=C(C=C3)[N+](=O)[O-])S(=O)(=O)[O-])N.[Na+].[Na+].

What is the InChIKey for disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

The InChIKey is ARZVLGVDYAMAFX-UHFFFAOYSA-L.

How many hydrogen bond donor counts does disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate have?

It has 2 hydrogen bond donor counts.

What is the hydrogen bond acceptor count of disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate?

The hydrogen bond acceptor count is 12.

How many covalently-bonded unit counts does disodium 6-amino-4-hydroxy-5-[(4-nitro-2-sulphonatophenyl)azo]naphthalene-2-sulphonate have?

It has 3 covalently-bonded unit counts.