Dichloro[(R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%

CAS

478308-91-7

Catalog Number

ACM478308917

Category

Other Products

Molecular Weight

1028.914g/mol

Molecular Formula

C52H50Cl2N4O4P2Ru;

MSDS COA Spec Sheet

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Specification

Synonyms

478308-91-7;MFCD06658133;DICHLORO[(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3, 3'-BIPYRIDINE][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II);DiCl[(R)-(+)-2,2',6,6'-tetraMeO-4,4'-bis(diphenylphosphino)-3,3'-bipyr][(1R,2R)-(+)-1,2-diphenylethylenediamine]Ru(II);

IUPAC Name

dichlororuthenium;(1R,2R)-1,2-diphenylethane-1,2-diamine;[3-(4-diphenylphosphanyl-2,6-dimethoxypyridin-3-yl)-2,6-dimethoxypyridin-4-yl]-diphenylphosphane;

Canonical SMILES

COC1=NC(=C(C(=C1)P(C2=CC=CC=C2)C3=CC=CC=C3)C4=C(N=C(C=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC)OC)OC.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.Cl[Ru]Cl;

InChI

InChI=1S/C38H34N2O4P2.C14H16N2.2ClH.Ru/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h5-26H,1-4H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1;

InChI Key

AKMYBLAYOREDRA-ODQAEMFESA-L;

Application

Effective catalyst for the highly enantioselective hydrogenation of a diverse range of simple aromatic ketones.

Complexity

944

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Exact Mass

1028.173g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

1028.173g/mol

Rotatable Bond Count

Topological Polar Surface Area

115A^2

January 20, 2023

A highly selective catalyst
Dichloro[(R)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) catalyst for oxidizing 1- olefins to aldehydes using air or oxygen.