Specification
Synonyms
RU(OAC)2[(R)-TOLBINAP]; 106681-15-6; Ru[(S)-T-BINAP](OCOCH3)2; Diacetato[(S)-(-)-2,2 inverted exclamation marka-bis(di-p-tolylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); DIACETATO[(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II); 116128-29-1; I14-34094; Diacetato[(R)-2,2 inverted exclamation marka-bis(di-p-tolylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); DIACETATO[(R)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II);
IUPAC Name
acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium;
Canonical SMILES
CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.CC(=O)O.CC(=O)O.[Ru];
InChI
InChI=1S/C48H40P2.2C2H4O2.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;2*1-2(3)4;/h5-32H,1-4H3;2*1H3,(H,3,4);;
InChI Key
OXESSJMVRGFBNX-UHFFFAOYSA-N;
Application
Catalyst system that exhibits high catalytic activity and enantioselectivity in the hydrogenation of enamines.
Covalently-Bonded Unit Count
4
Monoisotopic Mass
900.207g/mol
Topological Polar Surface Area
74.6A^2