Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I)

CAS

854045-93-5

Catalog Number

ACM854045935

Category

Gold series of catalysts

Molecular Weight

530.826g/mol

Molecular Formula

C20H27AuClP;

MSDS COA Spec Sheet

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Specification

Synonyms

SC10751; JohnPhos AuCl; [[1,1 inverted exclamation marka-Biphenyl]-2-ylbis(t-butylphosphine]chlorogold; AKOS024259177; Chloro[(1,1'-biphenyl-2-yl)di-tert-butylphosphine]gold(I), 98%; KS-000019BH; TRA0069872; Chloro[2-(di-t-butylphosphino)biphenyl]gold(I);

IUPAC Name

chlorogold;ditert-butyl-(2-phenylphenyl)phosphane;

Canonical SMILES

CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2)C(C)(C)C.Cl[Au];

InChI

InChI=1S/C20H27P.Au.ClH/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;;/h7-15H,1-6H3;;1H/q;+1;/p-1;

InChI Key

MZMOUYZCJIFYAH-UHFFFAOYSA-M;

Application

Highly active gold catalyst for the intramolecular exohydrofunctionalization of allenes.

Catalyst used for the hydroarylation of allenes.

Catalyst used for the intramolecular cyclization of monopropargyl triols.

Synthesis of pyrroles via a gold-catalyzed cascade reaction.

Gold-catalyzed carboalkoxylations of 2-ethynylbenzyl ethers.

Gold-catalyzed annulations of allenes with N-hydroxy anilines.

Complexity

302

Covalently-Bonded Unit Count

Exact Mass

530.12g/mol

Heavy Atom Count

Monoisotopic Mass

530.12g/mol

Rotatable Bond Count

Topological Polar Surface Area

0A^2