Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst

• CAS: 863971-63-5
• Catalog Number: ACM863971635
• Category: Ruthenium series catalysts
• Molecular Weight: 451.557g/mol
• Molecular Formula: C20H35N2OPRu
• Synonyms: 863971-63-5;Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II);DTXSID40856225;Ruthenium(2+) hydride (2E)-2-[(di-tert-butylphosphanyl)methylidene]-6-[(diethylamino)methyl]-2H-pyridin-1-ide--carbon monooxide (1/1/1/1)
• IUPAC Name: carbon monoxide;N-[[(6E)-6-(ditert-butylphosphanylmethylidene)pyridin-1-id-2-yl]methyl]-N-ethylethanamine;hydride;ruthenium(2+)
• Canonical SMILES: [H-].CCN(CC)CC1=CC=CC(=CP(C(C)(C)C)C(C)(C)C)[N-]1.[C-]#[O+].[Ru+2]
• InChI: InChI=1S/C19H34N2P.CO.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;/h11-13,15H,9-10,14H2,1-8H3;;;/q-1;;+2;-1/b17-15+
• InChI Key: FGPPOYVQHGYDJC-VHPYDAKRSA-N
• Application: Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.; ; Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.; ; Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.; ; Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.; ; Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone
• Complexity: 439
• Covalently-Bonded Unit Count: 4
• Defined Bond Stereocenter Count: 1
• Exact Mass: 452.153g/mol
• H-Bond Acceptor: 4
• Heavy Atom Count: 25
• Monoisotopic Mass: 452.153g/mol
• Rotatable Bond Count: 7
• Topological Polar Surface Area: 5.2A^2

Custom Reviews

April 6, 2023

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Excellent catalysts in electrochemical
Excellent catalytic electrochemical oxidation of ethanol to ethyl acetate and acetate

Custom Q&A

What is the Molecular formula of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)?

C20H35N2OPRu

What is the Molecular weight of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)?

451.553

What is the EC number of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)?

812-416-7

What is the Storage condition of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)?

Under inert gas (nitrogen or Argon) at 2-8°C

What is the Form of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)?

Solid

What is the Solubility in Water of Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)?

Insoluble