Benzotriazol-1-yloxytris(dimethylamino)-phosphonium hexafluorophosphate(bop)

• CAS: 56602-33-6
• Catalog Number: ACM56602336
• Category: Other Products
• Molecular Weight: 442.28
• Molecular Formula: C₁₂H₂₂F₆N₆OP₂
• Synonyms: Bop reagent, Btzo-tdmap, CID124335, ZINC04261883, LS-190188, Benzotriazol-1-yloxy-tris(dimethylamino)phosphonium, Benzotriazol-1-yloxy-tris(dimethylamino)phosphonium tetrafluoroborate, 56602-33-6, Benzotriazol-1-yloxy-tris(dimethylamino)phosphonium hexafluorophosphate, Phosphorus(1+), (1H-benzotriazol-1-olato-O)tris(N-methylmethanaminato)-, (T-4)-, 56602-32-5
• IUPAC Name: benzotriazol-1-yloxy-tris(dimethylamino)phosphanium
• Canonical SMILES: CN(C)[P+](N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1.F[P-](F)(F)(F)(F)F
• InChI Key: RROBIDXNTUAHFW-UHFFFAOYSA-N
• Melting Point: 136-140ºC
• Flash Point: 138°C
• Appearance: white to tan powder
• EC Number: 260-279-1
• Exact Mass: 442.12300
• Hazard Statements: Xi:Irritant
• H-Bond Acceptor: 7
• H-Bond Donor: 0
• Safety Description: S24/25
• Stability: Stable under normal temperatures and pressures.
• WGK Germany: 3

Synthetic Use

Upstream Synthesis Route 1

• 680-31-9

• 56602-33-6

Reference: [1] Phosphorus, Sulfur and Silicon and the Related Elements, 2003, vol. 178, # 2, p. 299 - 309

Upstream Synthesis Route 2

• 2592-95-2

• 56602-33-6

Reference: [1] Phosphorus, Sulfur and Silicon and the Related Elements, 2003, vol. 178, # 2, p. 299 - 309

Downstream Synthesis Route 1

• 491-36-1
• 56602-33-6

• 897930-10-8

Reference: [1]Organic Letters,2006,vol. 8,p. 2425 - 2428

Downstream Synthesis Route 2

• 890-38-0
• 56602-33-6

• 927818-52-8

Reference: [1]Journal of the American Chemical Society,2007,vol. 129,p. 782 - 789
[2]Patent: WO2008/45535,2008,A2 .Location in patent: Page/Page column 44-45
[3]Journal of Organic Chemistry,2010,vol. 75,p. 2461 - 2473

* For details of the synthesis route, please refer to the original source to ensure accuracy.