1-Allyl-3-methylimidazolium chloride

• CAS: 65039-10-3
• Catalog Number: ACM65039103
• Category: Functionized Ionic Liquids
• Molecular Weight: 158.63
• Molecular Formula: C7H11ClN2
• Description: 1-Allyl-3-methylimidazolium chloride is a thermostable and nonvolatile task-specific ionic liquid (TSIL). It shows high cellulose solubilization ability.
• Synonyms: AMIMCl
• IUPAC Name: 1-methyl-3-prop-2-enylimidazol-1-ium;chloride
• Canonical SMILES: C[N+]1=CN(C=C1)CC=C.[Cl-]
• InChI: 1S/C7H11N2.ClH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1
• InChI Key: QVRCRKLLQYOIKY-UHFFFAOYSA-M
• Melting Point: 38 °C
• Flash Point: Not applicable
• Appearance: Colorless to Brown clear liquid
• Application: Ionic liquid
• Storage: Store under inert gas, -20℃
• Abbreviation: AMIMCl
• Chemical Formula: [AMIM]Cl
• Complexity: 101
• Condition To Avoid: Air Sensitive,Heat Sensitive
• Covalently-Bonded Unit Count: 2
• Exact Mass: 158.061076g/mol
• Formal Charge: 0
• Hazard Statements: H315 : Causes skin irritation.H319 : Causes serious eye irritation.
• H-Bond Acceptor: 1
• H-Bond Donor: 0
• Heavy Atom Count: 10
• MDL Number: MFCD07784450
• Monoisotopic Mass: 158.061076g/mol
• Precautionary Statements: P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.
• Refractive Index: n20/D 1.578
• Rotatable Bond Count: 2
• Signal Word: Warning
• Specific Gravity: 1.39

Synthetic Use

Downstream Synthesis Route 1

• 65039-10-3
• 90076-65-6

• 655249-87-9

Reference: [1]Looser, Anna; Barmet, Christoph; Fox, Thomas; Blacque, Olivier; Gross, Simon; Nussbaum, Jennifer; Pruessmann, Klaas P.; Alberto, Roger
[Inorganic Chemistry, 2018, vol. 57, # 4, p. 2314 - 2319]
[2]Zajac, Adrian; Szpecht, Andrea; Szymanska, Anna; Zielinski, Dawid; Stolarska, Olga; Smiglak, Marcin; Maciejewski, Hieronim
[New Journal of Chemistry, 2020, vol. 44, # 28, p. 12274 - 12288]
[3]Rupp, Alexander; Roznyatovskaya, Nataliya; Scherer, Harald; Beichel, Witali; Klose, Petra; Sturm, Carola; Hoffmann, Anke; Tuebke, Jens; Koslowski, Thorsten; Krossing, Ingo
[Chemistry - A European Journal, 2014, vol. 20, # 31, p. 9794 - 9804]

* For details of the synthesis route, please refer to the original source to ensure accuracy.