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Structure

Acetylacetonatobis(cyclooctene)rhodium(I), min. 97%

CAS
34767-55-0
Catalog Number
ACM34767550
Category
Rhodium series of catalysts
Molecular Weight
423.422g/mol
Molecular Formula
C21H36O2Rh;

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Specification

Synonyms
ACETYLACETONATOBIS(CYCLOOCTENE)RHODIUM(I);34767-55-0;MFCD06658137;SC10118;ACETYLACETONATOBIS(CYCLOOCTENE)RHODIUM (I);BIS(CYCLOOCTENE)(2,4-PENTANEDIONATO)RHODIUM;
IUPAC Name
cyclooctane;(Z)-4-hydroxypent-3-en-2-one;rhodium;
Canonical SMILES
CC(=CC(=O)C)O.C1CCC[CH][CH]CC1.C1CCC[CH][CH]CC1.[Rh];
InChI
InChI=1S/2C8H14.C5H8O2.Rh/c2*1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h2*1-2H,3-8H2;3,6H,1-2H3;/b;;4-3-;;
InChI Key
PNMZHAUBWDEWCR-DVACKJPTSA-N;
Application
Rhodium source used in combination with phosphine ligands to catalyze the 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.

Rhodium source for the catalytic addition of arylboronic acids to N-tert-butanesulfinyl imino esters.
Complexity
147
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
1
Exact Mass
423.177g/mol
H-Bond Acceptor
2
H-Bond Donor
1
Heavy Atom Count
24
Monoisotopic Mass
423.177g/mol
Rotatable Bond Count
1
Topological Polar Surface Area
37.3A^2
January 20, 2023


Very effective in the synthesis of complexes.
In organic synthesis, ligand exchange of Acetylacetonatobis(cyclooctene)rhodium(I) has become an ideal target product.

What is molecular formula of Acetylacetonatobis(cyclooctene)rhodium(I)?

C21H35O2Rh

What is molecular weight of Acetylacetonatobis(cyclooctene)rhodium(I)?

422.413

What is the sensitivity of Acetylacetonatobis(cyclooctene)rhodium(I)?

Air sensitive

What are the storage conditions of Acetylacetonatobis(cyclooctene)rhodium(I)?

Under inert gas (nitrogen or Argon) at 2-8°C

What is topological polar surface area of Acetylacetonatobis(cyclooctene)rhodium(I)?

37.3 Ų

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