4'-Acetylbenzo-18-crown 6-ether

• CAS: 41855-35-0
• Catalog Number: ACM41855350
• Category: Other Products
• Molecular Weight: 354.39
• Molecular Formula: C₁₈H₂₆O₇
• Synonyms: 1-(2,5,8,11,14,17-hexaoxabicyclo[16.4.0]docosa-1(18),19,21-trien-20-yl)ethanone; 2,3-(4-Acetylbenzo)-1,4,7,10,13,16-hexaoxacyclooctadec-2-ene
• IUPAC Name: 1-(2,5,8,11,14,17-hexaoxabicyclo[16.4.0]docosa-1(18),19,21-trien-20-yl)ethanone
• Canonical SMILES: CC(=O)C1=CC2=C(C=C1)OCCOCCOCCOCCOCCO2
• InChI Key: GOVDFSVHYMATAJ-UHFFFAOYSA-N
• Boiling Point: 527.7ºC at 760 mmHg
• Melting Point: 77-78ºC
• Flash Point: 231.6ºC
• Density: 1.084g/cm³
• Exact Mass: 354.16800
• H-Bond Acceptor: 7
• H-Bond Donor: 0

Synthetic Use

Downstream Synthesis Route 1

• 60835-74-7
• 41855-35-0

• 135442-24-9

Reference: [1]Luboch; Cygan; Biernat
[Tetrahedron, 1991, vol. 47, # 24, p. 4101 - 4112]

Downstream Synthesis Route 2

• 41855-35-0

• 41757-97-5

Reference: [1]Talma, Auke G.; Vossen, Huib van; Sudhoelter, Ernst J. R.; Eerden, Johan van; Reinhoudt, David N.
[Synthesis, 1986, # 8, p. 680 - 683]

Downstream Synthesis Route 3

• 41855-35-0

• 76427-68-4

Reference: [1]Kikukawa, Kiyoshi; He, Gong-Xin; Abe, Akito; Goto, Tokio; Arata, Ryozo; et al.
[Journal of the Chemical Society. Perkin transactions II, 1987, p. 135 - 142]
[2]Paramonov, Sergey V.; Lokshin, Vladimir; Smolentsev, Artem B.; Glebov, Evgeni M.; Korolev, Valeri V.; Basok, Stepan S.; Lysenko, Konstantin A.; Delbaere, Stéphanie; Fedorova, Olga A.
[Tetrahedron, 2012, vol. 68, # 38, p. 7873 - 7883]

* For details of the synthesis route, please refer to the original source to ensure accuracy.