3-Trimethylsilyl-2-Oxazolidinone

• CAS: 43112-38-5
• Catalog Number: ACM43112385
• Category: Other Products
• Molecular Weight: 159.26 g/mol
• Molecular Formula: C6H13NO2Si
• Synonyms: TMSO, 3-Trimethylsilyl-2-oxazolidinone, N-Trimethylsilyl-2-oxazolidinone, 92771_FLUKA, NSC617258, 3-(Trimethylsilyl)oxazolidin-2-one, EINECS 256-098-2, CID123514, 2-Oxo-3-trimethylsilyl-1,3-oxazolidine, ST5411724, 43112-38-5, InChI=1/C6H13NO2Si/c1-10(2,3)7-4-5-9-6(7)8/h4-5H2,1-3H
• IUPAC Name: 3-trimethylsilyl-1,3-oxazolidin-2-one
• Canonical SMILES: C[Si](C)(C)N1CCOC1=O
• InChI Key: AUKCYOUETBBMFV-UHFFFAOYSA-N
• Boiling Point: 87ºC(0.8 torr)
• Flash Point: 76.7ºC
• Density: 1.04
• Storage: Moisture Sensitive. Ambient temperatures.
• EC Number: 256-098-2
• Exact Mass: 159.07200
• H-Bond Acceptor: 2
• H-Bond Donor: 0
• Safety Description: 24/25
• WGK Germany: 3

Synthetic Use

Upstream Synthesis Route 1

• 497-25-6
• 75-77-4

• 43112-38-5

Reference: [1]Palomo, C.
[Synthesis, 1981, # 10, p. 809 - 811]
[2]Aizpurua, Jesus Mari; Palomo, Claudio
[Bulletin de la Societe Chimique de France, 1982, vol. 2, # 7-8, p. 265 - 268]
[3]Kricheldorf,H.R.
[Justus Liebigs Annalen der Chemie, 1973, p. 772 - 792]

Upstream Synthesis Route 2

• 497-25-6
• 25436-07-1

• 43112-38-5

Reference: [1]Kricheldorf,H.R.
[Justus Liebigs Annalen der Chemie, 1973, p. 772 - 792]

Downstream Synthesis Route 1

• 43112-38-5
• 141-82-2

• 18457-04-0

Reference: [1] Synthesis, 1981, # 10, p. 809 - 811

Downstream Synthesis Route 2

• 67-56-1
• 43112-38-5

• 1825-61-2

Reference: [1]Renga, James M.; Pen-Chung, Wang
[Tetrahedron Letters, 1985, vol. 26, # 9, p. 1175 - 1178]

* For details of the synthesis route, please refer to the original source to ensure accuracy.