2,6-Bis[1-(2-methylphenylimino)ethyl]pyridine

• CAS: 210537-32-9
• Catalog Number: ACM210537329-1
• Category: Other Products
• Molecular Weight: 341.45
• Molecular Formula: C23H23N3
• Synonyms: N,N'-(2,6-Pyridinediyldiethylidyne)bis[2-methylbenzenamine
• IUPAC Name: 1-[6-[C-methyl-N-(2-methylphenyl)carbonimidoyl]pyridin-2-yl]-N-(2-methylphenyl)ethanimine
• Canonical SMILES: CC1=CC=CC=C1N=C(C)C2=NC(=CC=C2)C(=NC3=CC=CC=C3C)C
• InChI: FWPJMGBMVWKPTM-UHFFFAOYSA-N
• InChI Key: InChI=1S/C23H23N3/c1-16-10-5-7-12-20(16)24-18(3)22-14-9-15-23(26-22)19(4)25-21-13-8-6-11-17(21)2/h5-15H,1-4H3
• Boiling Point: 490.3±45.0 °C(Predicted)
• Appearance: Yellow powder
• Application: Ligand for iron catalyzed ethene polymerization, activated and heterogenized with a co-catalyst consisting of partially hydrolyzed trimethylaluminum on silica gel; ; Ligand for chromium catalyzed of ethylene oligomerization; ; Ligand for rhodium bis(imino)pyridine complex, that generates nanoparticles and effectively catalyses dehalogenation and hydrogenation of aromatic Compounds
• Complexity: 466
• Covalently-Bonded Unit Count: 1
• Exact Mass: 341.189g/mol
• H-Bond Acceptor: 3
• Heavy Atom Count: 26
• Isomeric SMILES: CC1=CC=CC=C1N=C(C)C2=NC(=CC=C2)C(=NC3=CC=CC=C3C)C
• Monoisotopic Mass: 341.189g/mol
• Rotatable Bond Count: 4
• Topological Polar Surface Area: 37.6A^2

Synthetic Use

Upstream Synthesis Route 1

• 1129-30-2
• 95-53-4

• 210537-32-9

Reference: [1]Journal of Molecular Catalysis A: Chemical,2011,vol. 340,p. 83 - 88
[2]Patent: US6103946,2000,A
[3]Polyhedron,2010,vol. 29,p. 2862 - 2866
[4]Inorganica Chimica Acta,2011,vol. 373,p. 47 - 53