(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III) chloride, 98%

CAS

250611-13-3

Catalog Number

ACM250611133

Category

Other Products

Molecular Weight

607.26

Molecular Formula

C36H52AlClN2O2

MSDS COA Spec Sheet

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Specification

IUPAC Name

aluminum;2,4-ditert-butyl-6-[[[(1R,2R)-2-[(3,5-ditert-butyl-6-oxocyclohexa-2,4-dien-1-ylidene)methylamino]cyclohexyl]amino]methylidene]cyclohexa-2,4-dien-1-one;trichloride

Canonical SMILES

CC(C)(C)C1=CC(=CNC2CCCCC2NC=C3C=C(C=C(C3=O)C(C)(C)C)C(C)(C)C)C(=O)C(=C1)C(C)(C)C.[Al+3].[Cl-].[Cl-].[Cl-]

InChI Key

QLSHFOGUVHXGGH-ZYOJYBKFSA-K

Melting Point

250-255ºC(lit.)

Application

Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.

Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.

Catalyst used for the asymmetric hydrocyanation of nitroolefins.

Catalyst used in the reaction of epoxides with heterocumulenes.

EC Number

607-518-1

Exact Mass

606.35300

Hazard Statements

Xn: Harmful;

Safety Description

26-36