1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

• CAS: 655249-87-9
• Catalog Number: ACM655249879
• Category: Other Products
• Molecular Weight: 403.32200
• Molecular Formula: C9H11F6N3O4S2
• Synonyms: AMIMNTF2;1-Allyl-3-methylimidazoliumbis(trifluoromethylsulfonyl)imide;1-allyl-3-imethylimidazoliumbis[(trifluoromethyl)sulfonyl]imide;1-Allyl-3-methylimidazoliumbis(trifluChemicalbookoromethylsulfonyl)imide;1-Allyl-3-methylimidazoliumBis(trifluoromethanesulfonyl)imide;bis(trifluoromethylsulfonyl)azanide:1-methyl-3-prop-2-enylimidazol-1-ium
• IUPAC Name: bis(trifluoromethylsulfonyl)azanide;1-methyl-3-prop-2-enylimidazol-1-ium
• Canonical SMILES: C[N+]1=CN(C=C1)CC=C.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• InChI Key: DHMWATGUEVQTIY-UHFFFAOYSA-N
• Density: 1.494 (29°C)
• Appearance: Colorless to light yellow liquid
• Application: Ionic liquid
• Storage: Store in a cool, dry and sealed place
• Exact Mass: 403.01000
• H-Bond Acceptor: 11
• H-Bond Donor: 0
• MDL Number: MFCD11109343
• Viscosity: 35 cP (25 °C)

Synthetic Use

Upstream Synthesis Route 1

• 90076-65-6

• 655249-87-9

Reference: [1]Location in patent: experimental part
Cvjetko, Marina; Vorkapić-Furač, Jasna; Žnidaršič-Plazl, Polona
[Process Biochemistry, 2012, vol. 47, # 9, p. 1344 - 1350]

Upstream Synthesis Route 2

• 65039-10-3
• 90076-65-6

• 655249-87-9

Reference: [1]Looser, Anna; Barmet, Christoph; Fox, Thomas; Blacque, Olivier; Gross, Simon; Nussbaum, Jennifer; Pruessmann, Klaas P.; Alberto, Roger
[Inorganic Chemistry, 2018, vol. 57, # 4, p. 2314 - 2319]
[2]Zajac, Adrian; Szpecht, Andrea; Szymanska, Anna; Zielinski, Dawid; Stolarska, Olga; Smiglak, Marcin; Maciejewski, Hieronim
[New Journal of Chemistry, 2020, vol. 44, # 28, p. 12274 - 12288]
[3]Rupp, Alexander; Roznyatovskaya, Nataliya; Scherer, Harald; Beichel, Witali; Klose, Petra; Sturm, Carola; Hoffmann, Anke; Tuebke, Jens; Koslowski, Thorsten; Krossing, Ingo
[Chemistry - A European Journal, 2014, vol. 20, # 31, p. 9794 - 9804]

Downstream Synthesis Route 1

• 96-27-5
• 655249-87-9

• 1337384-29-8

Reference: [1]O'Brien, Richard A.; Mirjafari, Arsalan; Jajam, Vijayakumari; Capley, Erin N.; Stenson, Alexandra C.; West, Kevin N.; Davis Jr., James H.
[Tetrahedron Letters, 2011, vol. 52, # 40, p. 5173 - 5175]

* For details of the synthesis route, please refer to the original source to ensure accuracy.