[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

• CAS: 79255-71-3
• Catalog Number: ACM79255713-1
• Category: Rhodium series of catalysts
• Molecular Weight: 724.4
• Molecular Formula: C36H40BF4P2Rh
• Synonyms: (1Z,5Z)-Cycloocta-1,5-diene;4-diphenylphosphanylbutyl(diphenyl)phosphane;rhodium;tetrafluoroborate
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;4-diphenylphosphanylbutyl(diphenyl)phosphane;rhodium;tetrafluoroborate
• Canonical SMILES: [B-](F)(F)(F)F.C1CC=CCCC=C1.C1=CC=C(C=C1)P(CCCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Rh]
• InChI: InChI=1S/C28H28P2.C8H12.BF4.Rh/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-12,15-22H,13-14,23-24H2;1-2,7-8H,3-6H2;/q;-1;/b;2-1-,8-7-
• InChI Key: CMOFFTCAXGHJOA-ONEVTFJLSA-N
• Melting Point: 205 °C
• Appearance: Powder
• Application: Catalyst used in the intramolecular, hydroamination of olefins.; ; Catalyst used for reductive aminations.
• Complexity: 453
• Covalently-Bonded Unit Count: 4
• Defined Bond Stereocenter Count: 2
• Exact Mass: 724.16894
• Formal Charge: -1
• H-Bond Acceptor: 5
• Heavy Atom Count: 44
• Hydrogen Bond Acceptor Count: 5
• Hydrogen Bond Donor Count: 0
• Isomeric SMILES: [B-](F)(F)(F)F.C1/C=C\CC/C=C\C1.C1=CC=C(C=C1)P(C2=CC=CC=C2)CCCCP(C3=CC=CC=C3)C4=CC=CC=C4.[Rh]
• Monoisotopic Mass: 724.16894
• Rotatable Bond Count: 9
• Topological Polar Surface Area: 0 Ų

Custom Reviews

January 20, 2023

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Good effect in enantioselective synthesis
[1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can efficiently catalyze asymmetric allyl amination to realize enantioselective synthesis of seven-membered nitrogen heterocycles.

Custom Q&A

What is the PubChem CID for [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

PubChem CID 10941595

What is the molecular formula of [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

C36H40BF4P2Rh

What is the molecular weight of [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

724.4 g/mol

When was [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate created in PubChem?

2006-10-26

What are some synonyms for [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

[Rh(dppb)(COD)]BF4, (1Z,5Z)-cycloocta-1,5-diene;4-diphenylphosphanylbutyl(diphenyl)phosphane;rhodium;tetrafluoroborate

What is the InChIKey for [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

CMOFFTCAXGHJOA-ONEVTFJLSA-N

What is the European Community (EC) Number for [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

632-827-3

How many hydrogen bond acceptor counts are there in [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

5

What is the topological polar surface area of [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

0-2

How many rotatable bond counts are there in [1,4-Bis(diphenylphosphino)butane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

9