1,4,7,10,13,16,19,22-Octaoxacyclotetracosane

• CAS: 33089-37-1
• Catalog Number: ACM33089371-2
• Category: Other Products
• Molecular Weight: 352.42
• Molecular Formula: C16H32O8
• Synonyms: 24-Crown 8-Ether
• IUPAC Name: 1,4,7,10,13,16,19,22-octaoxacyclotetracosane
• InChI: BGYBONWLWSMGNV-UHFFFAOYSA-N
• InChI Key: InChI=1S/C16H32O8/c1-2-18-5-6-20-9-10-22-13-14-24-16-15-23-12-11-21-8-7-19-4-3-17-1/h1-16H2
• Boiling Point: 497.6±40.0 °C(Predicted)
• Density: 0.995±0.06 g/cm3(Predicted)
• Appearance: Solid
• Isomeric SMILES: C1COCCOCCOCCOCCOCCOCCOCCO1

Synthetic Use

Upstream Synthesis Route 1

• 37860-51-8
• 112-60-7

• 33089-37-1

Reference: [1]Talanov, Vladimir S.; Bartsch, Richard A.
[Synthetic Communications, 1999, vol. 29, # 20, p. 3555 - 3560]
[2]Yamawaki, Junko; Ando, Takashi
[Chemistry Letters, 1980, p. 533 - 536]
[3]Clark, Paul G.; Guidry, Erin N.; Chan, Wing Yan; Steinmetz, Wayne E.; Grubbs, Robert H.
[Journal of the American Chemical Society, 2010, vol. 132, # 10, p. 3405 - 3412]
[4]Borodin, Oleg; Richter, Stefan; Robertson, Craig C.; Shchukin, Yevhenii; Von Delius, Max
[Journal of the American Chemical Society, 2021, vol. 143, # 40, p. 16448 - 16457]
[5]Beadle, James R.; Khanna, Raj K.; Gokel, George W.
[Journal of Organic Chemistry, 1983, vol. 48, # 8, p. 1242 - 1246]

Upstream Synthesis Route 2

• 37860-51-8
• 112-60-7

• 33089-37-1
• 71092-61-0

Reference: [1]Gibson, Harry W.; Bheda, Mukesh C.; Engen, Paul; Shen, Ya Xi; Sze, Jean; et al.
[Journal of Organic Chemistry, 1994, vol. 59, # 8, p. 2186 - 2196]

Upstream Synthesis Route 3

• 112-60-7

• 294-93-9
• 33089-37-1

Reference: [1]Kuo, Ping-Lin; Kawamura, Norio; Miki, Masaki; Okahara, Mitsuo
[Bulletin of the Chemical Society of Japan, 1980, vol. 53, # 6, p. 1689 - 1693]