(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh

• CAS: 213343-65-8
• Catalog Number: ACM213343658
• Category: Other Products
• Molecular Weight: 556.219g/mol
• Molecular Formula: C22H40BF4P2Rh-
• Synonyms: (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium(I) tetrafluoroborate; (-)-1,2-bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium (I) tetrafluoroborate; PUBCHEM_12964417; LKVIVYCYPYTYSO-ASDDUFFSSA-N; 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate; (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate; (S,S)-Me-BPE-Rh
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate
• Canonical SMILES: [B-](F)(F)(F)F.CC1CCC(P1CCP2C(CCC2C)C)C.C1CC=CCCC=C1.[Rh]
• InChI: InChI=1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m0.../s1
• InChI Key: LKVIVYCYPYTYSO-ASDDUFFSSA-N
• Application: The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
• Complexity: 277
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 4
• Defined Bond Stereocenter Count: 2
• Exact Mass: 556.169g/mol
• Formal Charge: -1
• H-Bond Acceptor: 5
• Heavy Atom Count: 30
• Monoisotopic Mass: 556.169g/mol
• Rotatable Bond Count: 3
• Topological Polar Surface Area: 0A^2

Custom Reviews

December 15, 2022

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Very good.
We bought this product, and got good result each time.