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Structure

(1,10-Phenanthroline)bis(triphenylphosphine)copper(I) nitrate dichloromethane adduct

CAS
33989-10-5
Catalog Number
ACM33989105
Category
Other Products
Molecular Weight
915.26
Molecular Formula
[Cu(C12H8N2)[P(C6H5)3]2]NO3 · 1/2CH2Cl2

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Specification

Synonyms
33989-10-5, SC10053, BIS COPPER NITRATEDICHLOROMETHANEADDUCT
IUPAC Name
copper(1+);dichloromethane;1,10-phenanthroline;triphenylphosphane;nitrate
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C(Cl)Cl.[N+](=O)([O-])[O-].[Cu+]
InChI Key
RMYGTLXCRLUAKL-UHFFFAOYSA-N
Application
High yield synthesis of 2-arylbenzo[b]furans via the copper (I) catalyzed coupling of o-iodophenols and aryl acetylenes.

High yield synthesis of vinyl sulfides.

Efficient synthesis of 1,3-enynes.

Effective synthesis of 2-substituted indoles.

Synthesis of 1,4-disubstituted 5-iodotriazoles.

Selective cyclization strategy to 2-substitued benzofurans and indoles.

Copper-catalyzed cascade reaction to 2-indolyl-C-glycosides.
Exact Mass
913.12200
H-Bond Acceptor
5
H-Bond Donor
0
Safety Description
26-36/37/39
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