1-Naphthalenecarboxamide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

CAS

174810-09-4

Catalog Number

ACM174810094

Category

Other Products

Molecular Weight

790.87

Molecular Formula

C₅₂H₄₄N₂O₂P₂

MSDS COA Spec Sheet

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Specification

Synonyms

(R,R)-DACH-naphthyl Trost ligand, 174810-09-4, (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL), N,N-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide), ROST LIGAND (NAPHTHYL), AC1MC0LT, KSC949Q0D, CTK8E9801, AKOS015911074, SC11308, KB-62533, I14-38451, (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N inverted exclamation marka-bis(2-diphenylphosphino-1-naphthoyl), 2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

IUPAC Name

2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

Canonical SMILES

C1CCC(C(C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9

InChI Key

VXFKMKXTPXVEMU-AWSIMMLFSA-N

Melting Point

224-231ºC

Exact Mass

790.28800

Hazard Statements

Xi:Irritant;

H-Bond Acceptor

H-Bond Donor

Safety Description

26-36/37/39

Upstream Synthesis Route 1

20439-47-8
178176-80-2

174810-09-4

Reference: [1]Trost, Barry M.; O'Boyle, Brendan M.
[Organic Letters, 2008, vol. 10, # 7, p. 1369 - 1372]
[2]Trost, Barry M.; Bunt, Richard C.; Lemoine, Remy C.; Calkins, Trevor L.
[Journal of the American Chemical Society, 2000, vol. 122, # 25, p. 5968 - 5976]

Upstream Synthesis Route 2

947-65-9

174810-09-4

Reference: [1]Trost, Barry M.; Bunt, Richard C.; Lemoine, Remy C.; Calkins, Trevor L.
[Journal of the American Chemical Society, 2000, vol. 122, # 25, p. 5968 - 5976]

Upstream Synthesis Route 3

178176-78-8

174810-09-4

Reference: [1]Trost, Barry M.; Bunt, Richard C.; Lemoine, Remy C.; Calkins, Trevor L.
[Journal of the American Chemical Society, 2000, vol. 122, # 25, p. 5968 - 5976]

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