2-Methyl-4,6-bis(octylsulfanylmethyl)phenol

CAS

110553-27-0

Catalog Number

ACM110553270

Category

Main Products

Molecular Weight

424.75

Molecular Formula

C₂₅H₄₄OS₂

MSDS COA Spec Sheet

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Specification

Synonyms

2-methyl-4,6-bis(octylsulfanylmethyl)phenol;4,6-bis (octylthiomethyl)-o-cresol;IRGANOX 1520;Phenol, 2-methyl-4,6-bis(octylthio)methyl-;2,4-BIS(OCTYLTHIOMETHYL)-6-METHYLPHENOL;2-METHYL-4,6-BIS((OCTYLTHIO)METHYL)PHENOL;2-methyl-4,6-[(octylthio)methyl]phenol;At 1520

IUPAC Name

2-methyl-4,6-bis(octylsulfanylmethyl)phenol

Canonical SMILES

CCCCCCCCSCC1=CC(=C(C(=C1)CSCCCCCCCC)O)C

InChI Key

GAODDBNJCKQQDY-UHFFFAOYSA-N

Boiling Point

532.2ºC at 760 mmHg

Flash Point

257.9ºC

Density

0.99 g/cm³

Appearance

white crystal or colorless to light yellow liquid

EC Number

402-860-6

Exact Mass

424.28300

Application of 2-Methyl-4,6-Bis(Octylsulfanylmethyl)Phenol as Antioxidant in Polybutadiene Polymerization

Kozak, Radosław, et al. International Journal of Polymer Analysis and Characterization, 2015, 20(7), 602-611.

A study explored the effect of Lewis base (σ complex) amine ether-type and ether-type polar modifiers on the microstructure of anionically polymerized polybutadiene. The strongest and comparable influence on 1,2 butadiene isomeric structure formation was provided by DMEAEE > DTP > THF-DEA. In this work, 2-Methyl-4,6-bis(octylsulfanylmethyl)phenol (Irganox 1520) was used as an antioxidant.
Polymerization of polybutadiene
· Three amine-ethers, DMEAEE, THF-DEA, and DMDEE, along with two ethers, ETE and DTP, were utilized as polar modifiers in the anionic polymerization of 1,3-butadiene.
· The impact of varying polar modifier concentrations in nonpolar solvents on polybutadiene microstructure was investigated through anionic polymerizations carried out in individual glass bottles using a custom bottle polymerizer.
· All reactions were conducted for 2 hours at a constant temperature of 70°C to ensure consistency in polybutadiene microstructure. Following the reaction, it was stopped with 0.5 mL of 2-propanol and an antioxidant (Irganox 1520) was added.
· The polymer solutions were then left overnight under a fume hood for solvent evaporation and subsequently dried in a vacuum dryer at 65°C and 10 mbar for the next 12 hours.

4,6-Bis (octylthiomethyl)-o-cresol as Antioxidant in Emulsion Polymerization of Isoprene

Minari, Roque J., et al. Journal of applied polymer science, 2010, 116(1), 590-601.

Polyisoprene (PI) can be prepared by batch seed-free emulsion polymerization of isoprene using n-dodecyl mercaptan as a chain transfer agent (CTA). In this work, three batch emulsion polymerizations of Is at 10 C were carried out, and a global polymerization model was adjusted to measurements of monomer conversion, particle diameter, and average molecular weights. During the synthesis process, 4,6-bis (octylthiomethyl)-o-cresol is used as an antioxidant to avoid latex degradation.
Polymerizations and characterization
· Initially, the emulsifier and 390 g of water were placed in the reactor. The temperature was then set to 10 °C, following which the monomer, CTA, and initiator were added, and the mixture was stirred for 30 min with continuous N2 bubbling. Polymerization began when a water solution of FeSO4.7H2O, SFS, and EDTA was introduced.
· Each latex sample was divided into three fractions. The first fraction was dried at 80 °C until a constant weight was achieved to measure conversion. The second fraction was diluted with water for particle size measurement. The third fraction underwent SEC characterization as follows: (a) an antioxidant [4,6-bis (octylthiomethyl)-o-cresol] was added to the latex to prevent degradation; (b) the latex was precipitated in isopropanol; and (c) the precipitate was filtered, dried under vacuum, and stored in the dark at 15 °C for analysis.

August 17, 2023

A new type of antioxidant
2-Methyl-4,6-bis(octylsulfanylmethyl)phenol is used in synthetic rubber, which has excellent antioxidant effect and its dosage is very small.

What is the material state of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

2-Methyl-4,6-bis(octylsulfanylmethyl)phenol is a white to light yellow oily liquid or crystal.

What is the main application of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

2-Methyl-4,6-bis(octylsulfanylmethyl)phenol is an environment-friendly antioxidant, which can be used to prepare rubber materials and improve the stability of materials.

What is the category of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

2-Methyl-4,6-bis(octylsulfanylmethyl)phenol is an organic raw material of phenolic alcohols and their halogenated, sulfonated, nitrated or nitrosated derivatives.

What is the melting point of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

The melting point of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol is 14.2℃.

What is the solubility of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

2-Methyl-4,6-bis(octylsulfanylmethyl)phenol can be dissolved in chloroform and methanol solvents.

What is the molecular formula of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

The molecular formula of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol is C25H44OS2.

What is the molecular weight of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

The molecular weight of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol is 424.75g/mol.

What are the storage conditions of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

2-Methyl-4,6-bis(octylsulfanylmethyl)phenol needs to be stored at low temperature.

What is 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

2-Methyl-4,6-bis(octylsulfanylmethyl)phenol is a new high molecular weight liquid antioxidant, which can improve the stability of plastics and realize the transformation of rubber products from universal to green.

What is the proportion of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol?

The specific gravity of 2-methyl-4,6-bis(octylsulfanylmethyl)phenol is 0.980 g/ml at 20℃.