2,3,4,6-Tetra-O-benzyl-D-gluconic acid-δ-lactone

• CAS: 13096-62-3
• Catalog Number: ACM13096623
• Category: Ethers
• Molecular Weight: 538.63
• Molecular Formula: C₂₄H₂₁NO₅
• Synonyms: 2,3,4,6-TETRAKIS-O-(PHENYLMETHYL)-D-GLUCONIC ACID LACTONE;2,3,4,6-TETRA-O-BENZYL-D-GLUCONO-1,5-LACTONE;2,3,4,6-Tetrakis-O-(phenylmethyl)-D-Gluconic Acid, D-Lactone;2,3,4,6-Tetra-O-benzyl-D-glucono-1;5-lactone
• IUPAC Name: (3R,4S,5R,6R)-3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-one
• Canonical SMILES: C1=CC=C(C=C1)COCC2C(C(C(C(=O)O2)OCC3=CC=CC=C3)OCC4=CC=CC=C4)OCC5=CC=CC=C5
• InChI Key: BUBVLQDEIIUIQG-NXVJRICRSA-N
• Exact Mass: 538.23600
• Hazard Statements: H410
• H-Bond Acceptor: 6
• H-Bond Donor: 0
• RIDADR: UN 2811 6.1 / PGIII
• Symbol: GHS09

Synthetic Use

Upstream Synthesis Route 1

• 6564-72-3

• 13096-62-3

Reference: [1] Patent: WO2005/92877, 2005, A1, . Location in patent: Page/Page column 63

Upstream Synthesis Route 2

• 59531-24-7

• 13096-62-3

Reference: [1] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 1, p. 642 - 644
[2] Organic Process Research and Development, 2014, vol. 18, # 1, p. 66 - 81
[3] Patent: US2005/209166, 2005, A1, . Location in patent: Page/Page column 26
[4] Patent: WO2006/138163, 2006, A2, . Location in patent: Page/Page column 25-26

Upstream Synthesis Route 3

• 4291-69-4

• 13096-62-3

Reference: [1] Tetrahedron Letters, 2002, vol. 43, # 40, p. 7271 - 7272

Upstream Synthesis Route 4

• 6564-72-3

• 13096-62-3

Reference: [1]Current Patent Assignee: CHINESE ACADEMY OF MEDICAL SCIENCES - CN105085494, 2019, B
Location in patent: Paragraph 0201; 0202; 0205

Downstream Synthesis Route 1

• 13096-62-3
• 1618-26-4

• 140658-49-7

Reference: [1]Journal of Organic Chemistry,1992,vol. 57,p. 3642 - 3650
[2]Tetrahedron Letters,2002,vol. 43,p. 7271 - 7272

* For details of the synthesis route, please refer to the original source to ensure accuracy.